一种含三苯基吡啶结构有机化合物的合成与性质研究

Synthesis and properties of one kind of organic compound containing acetophenine structure

以对甲基苯甲醛、苯乙酮、三苯胺单醛等为原料,利用水相Aldol缩合反应、固相Michael加成反应,设计合成了一种含有2,4,6-三苯基吡啶(简称C^N^C)结构单元的有机化合物(Y1)。运用傅立叶变换红外光谱、质谱、元素分析、核磁共振谱等手段进行了表征,同时研究了目标分子在六种不同极性溶剂中的紫外可见吸收和荧光发射性质。

Taking p-tolualdehyde, aeetopbenone, triphenylamine-aldehyde as raw materials, a new type of organic compound （ Y1 ） containing acetophenine（ shortened formC＇N＇C） structure was designed and synthesized by means of water phase Aldol condensation reaction and solid phase Michael addition reaction. The structure had been characterized by 1 H NMR, IR, MS and elemental analy- sis. The UV-visible and fluorescence emission properties in six different polarity solvent of the target molecules were tested.