摘要
以N,N-亚甲基双丙烯酰胺(N,N-MBA)为交联剂,过硫酸钾(KPS)为引发剂,采用交联共聚方法合成了具有pH敏感性的半互穿网络丙烯酰胺-co-丙烯酸水凝胶P(AAm-co-AA),利用水凝胶网络结构作为纳米反应器,自组装制备了纳米复合水凝胶P(AAm-co-AA)/Ag。水凝胶的溶胀行为研究表明,AAm与AA的质量比影响P(AAm-co-AA)/Ag水凝胶平衡溶胀率。
A pH-sensitive hydrogels with semi-interpenetrating networks (semi-IPN) composed of co-pol- ymer networks of acrylamide and acrylic acid P(AAm-co-AA) was synthesized by a cross-linking co-poly- merization route in the presence of N, N-methylene bisacrylamide (N,N-MBA) as crosslinker and potas- sium persuffate (KPS) as initiator. Silver nanoparticles have been self-assembled by using these hydrogel networks as a nanoreactor. The swelling behavior investigations demonstrated that the equipment swelling values of the P( AAm-co-AA)/Ag hydrogels were effected by the different ratios of AAm to AA.
出处
《应用化工》
CAS
CSCD
2013年第1期62-65,71,共5页
Applied Chemical Industry
基金
陕西省教育厅重点实验室基金项目(2010JS062)
延安大学自然科学专项基金(YD2012-08)