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LiCoPO_4电化学嵌锂行为研究 被引量：3

The electrochemistry of LiCoPO_4 as cathode in lithium ion battery
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摘要 综述了近年国内外对橄榄石结构的LiCoPO4电极材料的研究现状,包括其晶体结构、制备方法、导电性、磁性能以及电化学脱嵌锂行为。认为该材料的电化学脱嵌锂研究的理论基础意义更高于其实际应用,充电曲线上双电压平台存在的机理仍是公开的待解决难题。 In this paper, the recent situation on the study of the LiCoP（）4 cathode materials has been reviewed, including the crystallographic parameters, preparation technologies, electric con ductivity and electrochemical behavior. It is thought that the study of its electrochemical behavior has more significance in the theoretical investigation than its practical application in commercial lithium battery. The mechanism of the existence of two potential plateaus in the charging profile is still an open question.
作者 孟良荣 耿海龙 胡博 李慎范 徐艳辉
机构地区 苏州大学化学电源研究所 山东齐星新材料科技有限公司
出处 《电池工业》 CAS 2012年第4期244-248,253,共6页 Chinese Battery Industry
基金 江苏省自然科学基金项目(BK2009110)
关键词 锂离子电池 橄榄石结构 磷酸盐 导电率 Li ion battery olivine structure phosphate electric conductivity
分类号 TM912.9 [电气工程—电力电子与电力传动]
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参考文献22

  • 1徐艳辉.锂离子电池正极材料电化学[J].稀有金属材料与工程,2003,32(11):875-879. 被引量：17
  • 2Lin K Z,Xu Y H,He G R. The kinetic and thermodynamic analysis of Li ion in multi-walled carbon nanotubes[J].Materials Chemistry and Physics,2006.190-196.
  • 3Tarascon J M,Armand M. Issues and challenges facing rechargeablelithium batteries[J].Nature,2001.359-367.
  • 4Dell R M. Batteries fifty years of materials development[J].Solid State Ionics,2000.139-158.
  • 5Xu Y H,Wang G Y,Chen C P. The structure and electrode properties of non-stoichiometric A1.2 B2 type C14 Laves alloy and the effect of surface modificaton[J].International Journal of Hydrogen Energy,2007,(08):1050-1058.doi:10.1016/j.ijhydene.2006.07.007.
  • 6张倩,徐艳辉,王晓琳.不同Al含量α-Ni(OH)_2的制备及电化学性能研究[J].稀有金属材料与工程,2006,35(5):690-694. 被引量：7
  • 7Thackeray M. Lithium ion batteries:an unexpected conductor[J].Nature Materials,2002,(01):81-82.
  • 8Chung S Y,Bloking J T,Chiang Y M. Electronically conductive phospho-olivines as lithium storage electrodes[J].Nature Materials,2002,(01):123-128.
  • 9Howard W F,Spotnitz R M. Theoretical evaluation of high-energy lithium metal phosphate cathode materials in Li-ion batteries[J].Journal of Power Sources,2007.887-891.
  • 10Nyten A,Thomas J O. A neutron powder diffraction study of LiCoxFe1-xPO4 for x=0,0.25,0.40,0.60and 0.75[J].Solid State Ionics,2006.1327-1330.

二级参考文献33

  • 1张倩,徐艳辉,王晓琳,何国荣,林克芝.均相沉淀法制备α-Ni(OH)_2及其电化学性能研究[J].稀有金属材料与工程,2004,33(12):1291-1294. 被引量：12
  • 2[1]Amine K, Yasuda H, Yamachi M. J Power Sources[J],1999, 81 ～ 82:221
  • 3[2]Sakaebe H, Kageyama H, Ado K et al. J Power Sources[J],2001, 97 ～98:415
  • 4[3]Rakelboom E A, Nishimura K. J Power Sources[J], 2001,97 ～ 98:465
  • 5[4]Endo M, Kim C, Nishimura K et al. Carbon[J], 2000, 38:183
  • 6[7]Caurant D, Baffier N, Garcai B et al. Solid State Ionics[J],1996, 91:45
  • 7[8]Yamada O, Ishikawa M, Motita M et al. J Electrochimica Acta[J], 1999, 44: 1 607
  • 8[9]Nobili F, Tossici R, Groce F et al. J Power Sources[J],2001, 94:238
  • 9[10]Holzapfel M, Schreiner R, Ott A. J Electrochimica Acta[J],2001, 46: 1 063
  • 10[11]Yoshio M, Tanaka H, Tominaga K et al. J Power Sources[J], 1992, 40:347

共引文献21

同被引文献37

  • 1Zhao, Yujuan, Wang, Suijun, Zhao, Chunsong, Xia, Dingguo.Synthesis and electrochemical performance of LiCoPO_4 micron-rods by dispersant-aided hydrothermal method for lithium ion batteries[J].Rare Metals,2009,28(2):117-121. 被引量：11
  • 2Wu Q, Xu Y H, Ju H. New type low-cost cathode ma- terials for Li-ion batteries: Mikasaite-type Fe2 (SO4)3 [J]. Ionics, 2013, 19(3): 471-475.
  • 3Xu Y H, Wu J, Ju H. Reassessment of the role of Ag as the dopant in Li-ion cathode materials[J].J Electro- anal Chem, 2012, 681: 84-88.
  • 4Nanjundaswamy K S, Padhi A K, Goodenough J B,et al. Redox potential evaluation and electrochemical char- acteristics of NASICON-related-3D framework com- pounds[J]. Solid State Ionics, 1996, 92: 1-10.
  • 5Masquelier C, Padhi A K, Nanjundaswamy K S, et al. New cathode materials for rechargeable lithium batter- ies: The 3-D framework structures Li3Fe2 (XO4)3 (X= P, As)[J].J Solid State Chem, 1998, 1a5, 228-234.
  • 6Junichi S, Masanobu N, Masataka W,et al. Changes in electronic structure upon lithium insertion into Fe2 (SO4)3 and Fe2 (MOO4)3 investigated by X-ray absorp- tion spectroscopy[J]. J Phys Chem B, 2007, 111: 1424-1430.
  • 7Yokokawa H, Sakai N, Yamaji K, et al. Thermody- namic determining factors of the positive electrode po- tential of lithium batteries[J]. Solid State Ionics, 1998, 113-115:1-9.
  • 8Manthiram A, Goodenough J B. Lithium insertion into Fe2 (SO4)3 frameworks[J]. J Power Sources, 1989, 26: 403-408.
  • 9Ati M, Sougrati M T, Rousse R, et al. Single-step synthesis of FeSO4 F1-y OHy ( 0 ≤ y≤ 1 ) positive elec- trodes for Li-based batteries[J]. Chem Mater, 2012, 24: 1472-1485.
  • 10Okada S, Tonuma T, Uebo Y,et al. Anode properties of calcite-type MBOs (M: V, Fe) [J]. J Power Sources, 2003, 119-121: 621-625.

引证文献3

二级引证文献3

电池工业
2012年 第4期

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