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低温光-热双重固化材料的制备及其性能研究 被引量:4

Study on Preparation and Properties of Low Temperature UV-Heat Dual Curing Materials
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摘要 合成了既可以光固化又可以热固化的环氧丙烯酸酯,合成的树脂加入引发剂和促进剂后不仅在紫外光辐射下可以快速固化,而且仅在50℃加热的条件下也可在1 h内达到表干;研究了涂膜在单独光固化、单独热固化时固化涂膜的性能及其影响因素;红外光谱表明无论是光固化还是热固化,涂膜的固化程度均较高,凝胶含量可达到90.34%,且热重分析显示涂膜耐热性能良好。 An epoxy acrylate that could be both UV -cured and heat -cured has been synthesized. By adding photo initiator and accelerator in the resin, the resin can be cured under the UV light, as well as cured in an hour at 50 ℃. The influencing factors in UV - curing and heat - curing processes were investiga- ted, and the properties of the cured film were tested. The structure of the product was characterized by FT - IR. The heat resistance of the cured film was analyzed by DSC - TG. The results showed either UV - curing or heat - curing could give good properties and good heat resistance of the film.
出处 《涂料工业》 CAS CSCD 北大核心 2013年第2期48-51,共4页 Paint & Coatings Industry
关键词 低温 热固化 光固化 双重固化 low temperature heat curing UV curing properties research
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参考文献10

  • 1陈明,陈其道,肖善强,洪啸吟.混杂光固化体系的原理及应用[J].感光科学与光化学,2001,19(3):208-216. 被引量:33
  • 2HARALD H, ABDELKRIM E, ULRICH S S. Free radical and thermal curing of terpyridine - modified terpolyrners[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2004, 42 (16): 4028 -4035.
  • 3STUDER K, DECKER C. Redox and photoinitiated crosslinking polymerization: I. dual - cure isocyanate - acrylate system [ J]. Progress in Organic Coatings, 2005, 53 (2) : 126 -133.
  • 4AHMET N, TENG G H, MARK D S. Dual - curable unsaturated polyester inorganic/organic hybrid films[J]. Journal of Applied Polymer Science, 2006, 99 (i ) : 115 - 126.
  • 5刘红波,吴宗南.混杂紫外光固化研究进展[J].热固性树脂,2009,24(4):50-54. 被引量:9
  • 6丁伟,马家举,江棂,丁伟,马家举,江棂.紫外光和热双重固化对涂料性能的研究[J].淮北煤炭师范学院学报(自然科学版),2004,25(1):27-30. 被引量:9
  • 7李武成,王德海.光-热双重固化材料的制备及性能研究[J].化工新型材料,2008,36(2):13-15. 被引量:16
  • 8YOUNG J P, DONG H L, HYUN J K, et al. UV - and thermal- curing behaviors of dual - curable adhesives based on epoxy acrylate 01- igomers] J]. International Journal of Adhesion & Adhesives, 2009, 29 : 710 - 717 .
  • 9NAOYA SAIKI, SAYAKA KAINOU, HIRONORI SHIZUHATA, et al , Ultraviolet/heat dual - curable film adhesives with pendant aeryloyl functional group modified epoxy resin [J J. Journal of Applied Polymer Science,2010, 117 :3466 -3472.
  • 10姚梅,王汝敏,董萌.紫外光固化体系的研究进展[J].中国胶粘剂,2006,15(6):33-36. 被引量:19

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