钴席夫碱螯合物及其氧加合物热重分析研究

Thermal Gravimetry Analysis Study on Cobalt Schiff Bases Complex and Its Dioxygen Adult

对合成的钴（Ⅱ）席夫碱螯合物CoL1[CoL1=邻苯二胶双缩-1-苯基-3-甲基-4苯甲酸基吡唑啉酮-5合钴（Ⅱ）]、钴（Ⅱ）席夫碱螯合物Co（Ⅱ）L3[Co（Ⅱ）L3=乙二胺双缩-1-乙酰萘酚合钴（Ⅱ）及其氧加合物[Co（Ⅱ）L5·PY·O2·2H2O]进行热重分析研究，与其它的分析测试方法综合，对合成的化合物进行组成和结构的说明，并对其结构作初步推断．

In this paper we report the syntheses of Co(ⅡOL1(L1= N, N' - phenylene bis(1-pheny1 - 2 - methy1 - 4 - benzoy liminepyraxolone - 5), Co(Ⅱ)L3(L3 = N, N' - 1, 2 - ethylene bis(1 -acetylnaphthol- 1) and its oxygen adult Co(ⅡOL3·PY·O2· 2H2O, and thermal date of the complexes and its addult. Their structures and composations can be determinted by the results of the TGA and other methods of experiments.