摘要
合成了发光性能良好的稀土元素 (铕、铽 )的对甲苯基丁基亚砜 (TBSO)高氯酸盐配合物 ,通过元素分析、红外光谱、紫外光谱 ,电导率对其进行了表征 ,分析表明配合物的化学式为 [L n(TBSO) n][Cl O4 ]3 (L n =Eu,n=7;Ln =Tb,n=6 ) ,并研究了其中稀土离子的荧光光谱 .
In this paper complexes of lanthanide (Eu,Tb) perchlorate with p-methyl-phenyl-butyl sulfoxide have been prepared and characterized by elemental analysis, FT-IR, UV, molar conductivcities and chemical analysis. From the results of elemental analysis the complex formula is found to be [Ln(TBSO) n ][ClO 4] 3 (Ln=Eu, n =7;Ln=Tb, n =6).The luminescent properties of the complexes with Eu, Tb are reported.
出处
《南京师大学报（自然科学版）》
CAS
CSCD
2000年第2期60-64,共5页
Journal of Nanjing Normal University(Natural Science Edition)
关键词
稀土高氯酸盐配合物
铕
铽
合成
表征
荧光光谱
lanthanide (Eu,Tb) perchlorate complex
p methyl phenyl butyl sulfoxide
synthesis
characterization
luminescent property
