期刊文献+

钴-均苯三甲酸配合物的热力学性能、热稳定性及其传感性能的研究

下载PDF
导出
摘要 用水热法合成了配合物钴-均苯三甲酸并做了其粉末X射线衍射和红外光谱的表征。本文首次用调制式差示扫描量热仪测量了配合物低温下的摩尔热容。计算出配合物在298.15K时的摩尔热容是526.3 J mol-1K-1。基于在298.15K时的摩尔热容数据推导出配合物的热力学参数如熵和焓。此外,用热重测量了配合物的热稳定性,配合物在393.15K时开始分解。
出处 《黑龙江科技信息》 2013年第2期36-37,共2页 Heilongjiang Science and Technology Information
  • 相关文献

参考文献16

  • 1Murray LJ,Dinca M,Long JR,Hydrogen storage in metal-or-ganic frameworks,Chem Soc Rev.38(2009)1294-314.
  • 2Lee J,Farha OK,Roberts J,Scheidt KA,Nguyen ST,HuppJT,Metal-organic framework materials as catalysts,Chem Soc Rev.38(2009)1450-9.
  • 3Liu YY,Zhang J,Xu F,Sun LX,Zhang T,You WS,et al,Lithium-based 3D coordination polymer with hydrophilic structurefor sensing of solvent molecules,Cryst Growth Des.8(2008)3127-9.
  • 4Bae YS,Mulfort KL,Frost H,Ryan P,Punnathanam S,Broad-belt LJ,et al,Separation of CO2 from CH4 using mixed-ligandmetal-organic frameworks,Langmuir.24(2008)8592-8.
  • 5Contreras R,Flores-Parra A,Mijangos E,Tellez F,Lopez-Sandoval H,Barba-Behrens N,From mono to polydentate azoleand benzazole derivatives,versatile ligands for main group andtransition metal atoms,Coordin Chem Rev.253(2009)1979-99.
  • 6Nidhuban Deb,Some heterobimetallic oxalate coordination pre-cursors of lanthanum(III)of the type,M3[La(C2O4)3(H2O)m]2.nH2O(M=Mn(II),Co(II),Ni(II)and Cu(II)),J Therm Anal Calorim.107(2012)561-571.
  • 7Song LF,Jiang CH,Jiao CL,Zhang J,Sun LX,Xu F,JiaoQZ,Xing YH,Du Y,Cao Z,Huang FL,Heat capacities and ther-modynamic properties of one manganese-based MOFs,J.Therm.Anal.Calorim.,102(2010)1161-6.
  • 8Chun-Hong Jiang,Li-Fang Song,Cheng-Li Jiao,JianZhang,Li-Xian Sun,Fen Xu,Exceptional thermal stability andthermodynamic properties of lithium based metal-organic framework,J Therm Anal Calorim.103(2011)373-380.
  • 9Liu Yang,Paul Thomas,Barbara Stuart,Discrimination ofthermally treated low density polyethylenes using DSC and princi-pal component analysis,J Therm Anal Calorim.108(2012)445-448.
  • 10Reading M,Luget A,Wilson R,Modulated Differential Scan-ning Calorimetry,Thermochim Acta.238(1994)295-307.

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部