摘要
用热重分析法研究了尼龙69在N2气氛中不同升温速率(β)下的热降解反应动力学.尼龙69在N2中的降解反应过程为一步反应,降解温度随β的升高线性升高.用Kissinger法、Flynn-Wall-Ozawa法和Coats-Redfern法求得降解反应的活化能分别为242.9,244.0,249.9kJ/mol,表观指前因子平均值为1015.52.用Coats-Redfern法证明了尼龙69的热降解反应为相边界反应.
This paper studied the kinetics rates(β) in N2 atmosphere by thermograv of nylon 69 was one step reaction in N2 increasing of the ft. Kissinger, Flynn- of thermal degradation of lmetrlc and the -Wall-O respectively to determine the apparent activation analysis(TG). degradation t zawa and Co energy of the and 242.9, 244.0, 249.9 kJ/mol were obtained fro value of the apparent pre-exponential factor was 10^15.52 confirmed as contracting surface reaction by Coats-R nylon 69 at different heating e thermal degradation process emperature rose linearly with the ats-Redfern methods were used thermal degradation of nylon 69, those methods respectively. The average The thermal degradation mechanism was edfern method.
出处
《浙江工业大学学报》
CAS
2013年第1期13-16,共4页
Journal of Zhejiang University of Technology
关键词
尼龙69
动力学
热降解机理
活化能
nylon 69
kinetics
thermal degradation mechanism
activation energy