摘要
Enantiomerically pure sultams (-)-2, (+)-3 and (+)-4 were synthesized.Their uses as new chiral auxiliaries in asymmetric Diels-Alder reactions with diastereoselectivity up to 99∶1 are presented. The relationship between the structure of chiral sultam and the effectiveness of asymmetric induction in Diels-Alder reactions are also discussed.
Enantiomerically pure sultams (-)-2, (+)-3 and (+)-4 were synthesized.Their uses as new chiral auxiliaries in asymmetric Diels-Alder reactions with diastereoselectivity up to 99∶1 are presented. The relationship between the structure of chiral sultam and the effectiveness of asymmetric induction in Diels-Alder reactions are also discussed.
出处
《中山大学学报(自然科学版)》
CAS
CSCD
北大核心
2000年第4期131-132,共2页
Acta Scientiarum Naturalium Universitatis Sunyatseni
基金
香港浸会大学基金资助项目
香港研究资助局基金资助项目