ω-溴代酰胺基邻菲咯啉化合物的合成和表征

Synthesis and Characterization of 5 (ω Bromo alkyl Amide) 1,10 Phenanthroline Derivatives

合成 4种新的 5- ( ω-溴代酰胺基 ) - 1 ,1 0 -菲咯啉化合物 phen- NHCO( CH2 ) n Br( n=1 ,3～ 5) ,它们是钌 ( )类电化学发光 ( ECL)传感器活性材料的配体 .利用元素分析、红外光谱、核磁共振氢谱和激光解析电离飞行时间质谱确证其组成和结构 .

amino 1,10 phenanthroline and four new 1,10 phenanthroline derivatives 5 substituted by ω bromo alkyl amides, phen NHCO(CH 2) n Br ( n =1, 3～5) were synthesized and characterized by elemental analysis, IR, 1H NMR, and ESI MS. These new compounds are important ligands of active materials of Ru(Ⅱ) ECL sensors.