摘要
Ethylenediamine (H2NCH2CHeNH2) was found to be a highly effective catalyst for the condensation of aryl aldehydes with nitromethane (or nitroethane). When 1%-2% (tool%) of ethylenediamine was used as the catalyst, the one-pot reaction of aryl aldehydes with nitromethane (or nitroethane) by refluxing for 3-10 h efficiently afforded various arylnitroalkenes la-ly in 85%-97% yields.
Ethylenediamine (H2NCH2CHeNH2) was found to be a highly effective catalyst for the condensation of aryl aldehydes with nitromethane (or nitroethane). When 1%-2% (tool%) of ethylenediamine was used as the catalyst, the one-pot reaction of aryl aldehydes with nitromethane (or nitroethane) by refluxing for 3-10 h efficiently afforded various arylnitroalkenes la-ly in 85%-97% yields.
基金
the National Natural Science Foundation of China (No. 20972048) and Shanghai Educational Development Foundation (The Dawn Program: No. 03SG27) for the financial support of this work.