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Synthesis and Crystal Structure of 3-Methyl-10-(4-nitrophenyl)-7,8,10,10a-tetrahydropyrano[4,3-b]chromene-1,9(4aH,6H)-dione

Synthesis and Crystal Structure of 3-Methyl-10-(4-nitrophenyl)-7,8,10,10a-tetrahydropyrano[4,3-b]chromene-1,9(4aH,6H)-dione
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摘要 The title compound (C19H15NO6) was synthesized via a three-component reaction and characterized by means of IR and 1H NMR. Its crystal and molecular structures were determined by X-ray diffractometry. It belongs to the monoclinic system, space group P21/c with a = 11.670(3), b = 12.076(3), c = 11.613(3), β = 99.490(4)°, V = 1614.2(7)3, Mr = 353.32, Z = 4, Dc = 1.454 g/cm3, λ = 0.71073, μ = 0.110 mm-1, F(000) = 736, the final R = 0.0503 and wR = 0.1311. A total of 8454 reflections were collected, of which 3497 were independent (Rint = 0.0333) and 2102 were observed with I 2σ(I). The title compound (C19H15NO6) was synthesized via a three-component reaction and characterized by means of IR and 1H NMR. Its crystal and molecular structures were determined by X-ray diffractometry. It belongs to the monoclinic system, space group P21/c with a = 11.670(3), b = 12.076(3), c = 11.613(3), β = 99.490(4)°, V = 1614.2(7)3, Mr = 353.32, Z = 4, Dc = 1.454 g/cm3, λ = 0.71073, μ = 0.110 mm-1, F(000) = 736, the final R = 0.0503 and wR = 0.1311. A total of 8454 reflections were collected, of which 3497 were independent (Rint = 0.0333) and 2102 were observed with I 2σ(I).
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2013年第1期73-76,共4页 结构化学(英文)
基金 supported by the National Natural Science Foundation of China(No.81071144) Natural Science Foundation of Guangdong Province(No.9451806001002961)
关键词 multicomponent reaction XANTHENE crystal structure multicomponent reaction xanthene crystal structure
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