摘要
Single-hole hollow polymer nanospheres were fabricated by raspberry-like template method using ＂graft-from＂ strategy through atom transfer radical polymerization （ATRP）. Nanometer-sized silica spheres were covalently attached onto the surfaces of micrometer-sized silica spheres. Crosslinked polymer shells on the nano-sized spheres outside the attached area were formed by ＂graft-from＂ strategy through ATRP. After removal of the silica cores, single-hole hollow crosslinked polymer nanospheres were obtained. In this strategy, most of ATRP monomers may be used and thus many functional groups can be easily incorporated into the single-hole hollow crosslinked polymer nanospheres.
Single-hole hollow polymer nanospheres were fabricated by raspberry-like template method using ＂graft-from＂ strategy through atom transfer radical polymerization （ATRP）. Nanometer-sized silica spheres were covalently attached onto the surfaces of micrometer-sized silica spheres. Crosslinked polymer shells on the nano-sized spheres outside the attached area were formed by ＂graft-from＂ strategy through ATRP. After removal of the silica cores, single-hole hollow crosslinked polymer nanospheres were obtained. In this strategy, most of ATRP monomers may be used and thus many functional groups can be easily incorporated into the single-hole hollow crosslinked polymer nanospheres.
基金
supported by the National Natural Science Foundation of China (No. 20974052)
the Natural Science Foundation of Tianjin Municipality (No. 09JCZDJC22900)
