摘要
Two new piperazine templated lanthanide sulfates (C4N2HI2)1.5[Ln(SO4)3(H20)]H20[Ln=Gd(1), Tb(2)] have been synthesized solvothermally and structurally characterized by single crystal X-ray diffraction(XRD), infrared(IR) spectroscopy, thermal analysis, fluorescent spectra and inductively coupled plasma(ICP). Single crystal X-ray diffraction reveals that both compounds 1 and 2 crystallized in the monoclinic crystal system, with space group P2t/c and cell dimensions: a=0.64468(19) nm, b=2.9979(9) nm, c=0.9818(3) nm, fl=101.271(4), V=l.8608(10) nm3, Z=4 for compound 1; a=0.64259(19) nm, b=3.0010(9) rim, c=0.9812(3) nm, fl=101.229(4), V=1.8560(10) nm3, Z=4 for compound 2. Compounds 1 and 2 are isomorphous and have similar 2D corrugated inorganic frameworks fabricated via the connection of single chains and $204 groups, while fully protonated piperazine cations and water molecules are located between the inorganic layers. The solid state luminescent properties of compound 2 were investigated and it displayed a typical luminescent property of Tb3+ with excitation wavelength at 371 nm.
Two new piperazine templated lanthanide sulfates (C4N2HI2)1.5[Ln(SO4)3(H20)]H20[Ln=Gd(1), Tb(2)] have been synthesized solvothermally and structurally characterized by single crystal X-ray diffraction(XRD), infrared(IR) spectroscopy, thermal analysis, fluorescent spectra and inductively coupled plasma(ICP). Single crystal X-ray diffraction reveals that both compounds 1 and 2 crystallized in the monoclinic crystal system, with space group P2t/c and cell dimensions: a=0.64468(19) nm, b=2.9979(9) nm, c=0.9818(3) nm, fl=101.271(4), V=l.8608(10) nm3, Z=4 for compound 1; a=0.64259(19) nm, b=3.0010(9) rim, c=0.9812(3) nm, fl=101.229(4), V=1.8560(10) nm3, Z=4 for compound 2. Compounds 1 and 2 are isomorphous and have similar 2D corrugated inorganic frameworks fabricated via the connection of single chains and $204 groups, while fully protonated piperazine cations and water molecules are located between the inorganic layers. The solid state luminescent properties of compound 2 were investigated and it displayed a typical luminescent property of Tb3+ with excitation wavelength at 371 nm.
基金
Supported by the Natural Science Foundation of Jiangsu Province of China(No.BK2012823).