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天津市可吸入颗粒物及元素室内外相关性 被引量:30

Residential indoor-outdoor relationships of PM10 and elements in Tianjin
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摘要 选取天津市某社区作为采样点,于2009年8、9月(代表非采暖季)和11、12月(代表采暖季)采集了室内和室外可吸入颗粒物(PM。0)样品,以研究天津市PMl0及元素的室内外相关性.结果表明,采暖季PMlo的室外平均浓度为198.88μg/m3.非采暖季和采暖季PMl0的室内外浓度LL(I/O比值)的变化范围分别为0.14~3.22和0.10-3.70,平均值分别为0.88和O.96,室内外相关系数(R2)分别为0.32和0.46.AI、Ca、Fe等元素的浓度均高于1μg/m3,V、Mn、Cu等元素浓度变化范围为0.01~1Hg/m3;非采暖季和采暖季元素I/O比值的变化范围分别为0.62~1.04和0.41加.92.以采暖季为例,使用PMl0质量(元素)浓度的质量平衡模型计算的有效穿透因子(Find、贡献值、贡献率分别为0.26(0.39)、50.84μg/m3(78.69μg/m0)、43.97%(50.05%),两种结果存在差异的原因是2种模型对E。f的假设不同. In order to investigate the relationships of indoor and outdoor particulate matter (PM10) in Tianjin, researchers collected indoor and outdoor PMI0 samples in a community in 2009 August, September(represent non-heating season), November and December (represent heating season). The results demonstrate that the average concentration of PM10 in heating season is 198.88gg/m3. The variation ranges of PM10 indoor-outdoor ratio in non-heating and heating season are 0.14-3.22 and 0.10~3.70, respectively, and the average values are 0.88 and 0.98, respectively. The correlation coefficients of indoor and outdoor PM10 are 0.32 and 0.46 in non-heating and heating seasons, respectively. The concentrations of several elements, such as aluminum, calcium and iron, are exceeding 1 μg/m3. The variation range of concentrations of vanadium, manganese and copper is from 0.01μg/m3 to lμg/m3. The non-heating season and heating season elements I/O value variation range are 0.62-1.04 and 0.41-0.92. Take heating season for example, the infiltration factor (For), contribution and contribution rate calculated by mass balance model using PM10 mass concentrations (element) are 0.26(0.39),50.84μg/mS(78.69μg/m3), 43.97%(50.05%), respectively. The difference between both results attributes to the different assumin,s on infiltration factor.
出处 《中国环境科学》 EI CAS CSCD 北大核心 2013年第2期357-364,共8页 China Environmental Science
基金 国家自然科学基金资助项目(20977054)
关键词 PM10 元素 室内外浓度比 室内外相关系数 质量平衡模型 PM10 elements I/Oratio indoor-outdoorcorrelationcoefficient~ mass balancemodel
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参考文献11

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