摘要
扬子石化芳烃装置C10+A产量达200~250 t/d,重芳烃未得到有效利用,提高重芳烃资源利用的空间较大。将歧化单元催化剂更换为HAT-099催化剂后,通过对甲苯塔、重芳烃塔和邻二甲苯塔的操作工况进行调整优化,提高了歧化单元进料中重芳烃含量,优化了进料组成结构,使歧化装置进料中甲苯,C9A和C10+A的质量比56:32:8调整为51:37:9。通过优化歧化单元反应工艺条件,有效提高了重芳烃转化率和二甲苯收率,其歧化单元多处理C10+A约45 t/d,C8A多产出约150 t/d。以目标产品计,装置综合能耗由优化调整前的69.40 kg/t降低至优化调整后的67.34 kg/t。
The production of C10^+A from the aromatics plant of Yangzi Petrochemical Company was 200-250 t/d, but the heavy aromatics resource was not utilized effectively. In order to solve the problem, Yangzi Petrochemical Company replaced the catalyst of disproportionation unit with HAT-099 catalyst, optimized the operational conditions of toluene column, heavy aromatics column, and o-xylene column, increased the content of C10^+A in the feed stock, optimized the composition of feed, and increased the mass ratio of toluene to CgA and C10^+A in feed of disproportionation unit from 56:32:8 to 51:37:9. The results showed that optimization of process conditions for disproportionation unit led to higher conversion of heavy aromatics and higher yield ofxylene. The treatment capacity for C10^+A increased by about 45 t/d, the production capacity of C10^+A increased by 150 t/d and the energy consumption decreased from 69.40 to 67.34 kg/t(the energy consumption was calculated by the consumption of standard oil for producing per ton of benzene and C8A).
出处
《化学反应工程与工艺》
CAS
CSCD
北大核心
2012年第6期557-563,共7页
Chemical Reaction Engineering and Technology
关键词
重芳烃
芳烃歧化
邻二甲苯
heavy aromatics
aromatics disproportionation
o-xylene