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Effective synthesis of benzyl halides triggered by in situ prepared hypervalent halides 被引量:3

Effective synthesis of benzyl halides triggered by in situ prepared hypervalent halides
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摘要 为直接 benzylhalogenation 与的一条有效途径在 hypervalent 的 situ 产生,卤化物被开发了。许多本甲基卤化物被生产在对有高 regioselectivities 的优秀收益(多达 99%) 中等。紫外吸收光谱被采用检测 tert 丁基 hypoiodite 的形成。 An effective approach for the direct benzylhalogenation with in situ generation of hypervalent halides has been developed. A variety of benzyl halides are produced in moderate to excellent yields (up to 99%) with high regioselectivities. UV absorption spectrum is employed to detect the formation of tert-butyl hypoiodite.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2013年第1期45-48,共4页 中国化学快报(英文版)
基金 Fundings of the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry,China-France Le Programme Xu Guangqi (No.27967RE) Chongqing University(No.CDJRC10220004 and No. CDJZR11220005) Natural Science Foundation Project of CQ CSTC (No.2010BB5064) for financial support
关键词 卤化物 卤代物 原位制备 有效合成 苄基 引发 紫外吸收光谱 区域选择性 Benzyl halidesBrominationHypervalentlodination
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