期刊文献+

Zn(MAA)_2添加方式对CM性能的影响

Effects of Zinc Dimethacrylate's Adding Methods on Propeties of CM
下载PDF
导出
摘要 考察了甲基丙烯酸锌(Zn(MAA)2)添加方式对CM性能的影响。结果表明,Zn(MAA)2用量相同时,原位生成Zn(MAA)2的胶料力学性能优于直接添加Zn(MAA)2的胶料;随着Zn(MAA)2用量的增大,胶料硫化程度明显提高,力学性能得到明显改善,老化后的拉伸性能保持率也得到改善;Zn(MAA)2用量在30~40份之间时,拉伸强度可达到19.7MPa,撕裂强度提高3倍以上。 Effects of different adding methods of Zinc Dimethaerylate[Zn(MAA)2 ] on the prperties of chlorinated polyethylene rubber (CM) were investigated. The results showed that the comprehen- sive mechanical properties of CM vulcanizate with Zn(MAA)2 generated in-situ was superior to that with Zn(MAA)2 added directly when the amount of Zn(MAA)2 addition was equal. The crosslinking degree of CM vulcanizate was significantly improved with the increase of Zn(MAA)2 amount, and the mechanical properties and the tensile properties retention became good. The tensile strength could reach 19.7MPa,and the tear strength also increased more than three times when Zn(MAA)2 content was 30-40 phr.
出处 《特种橡胶制品》 2013年第1期5-8,共4页 Special Purpose Rubber Products
基金 国家自然科学基金和国家863计划项目 该研究成果已实现产业化并获得上海市2010年度科技发明二等奖
关键词 甲基丙烯酸锌 CM 添加方式 力学性能 zinc dimethacrylate CM adding methods mechanical properties
  • 相关文献

参考文献7

二级参考文献25

  • 1关玉坤,徐晓东.金属活性助剂MCA对丁腈橡胶性能的影响[J].特种橡胶制品,1995,16(3):5-7. 被引量:5
  • 2张明,陈中俊,山田英介,稻垣慎二,尾之内千夫,冈本弘.羧酸铝对橡胶的增强作用[J].合成橡胶工业,1996,19(4):248-251. 被引量:4
  • 3王聿衡,彭宗林,张勇,张隐西.原位生成ZDMA补强HNBR性能的研究[J].橡胶工业,2006,53(1):10-15. 被引量:11
  • 4史振学,李梅,柳召刚,胡艳宏.稀土在橡胶生产中的应用[J].稀土,2006,27(2):75-80. 被引量:26
  • 5袁新恒.不饱和羧酸金属盐补强SBR的研究[M].上海:上海交通大学,1999..
  • 6Lu Yonglai, Liu Li, Yang Cheng, et al. The morphology of zinc dimethacrylate reinforced elastomer investigated by SEM and TEM [ J ]. European Polymer Journal,2005,41 ( 3 ) : 577 - 588.
  • 7Young J. In situ-formation of zinc dimethacrylate for the reinforcement of ethylene-propylene-diene rubber ( EPDM ) [ D ]. Ohio : University of Akron ,2005.
  • 8Wen Shipeng, Zhang Xiaoping, Hu Shui, et al. Influence of in-situ reaction on luminescent properties of samarium-complex/hydrogenated aerylonitrile-butadiene composites[ J]. Polymer,2009,50(14) :3269 - 3274.
  • 9Liu Li, Lei He, Cheng Yang, et al. In-situ reaction and radiation protection proerties of Gd ( AA )3/NR/composites [ J ] . Macromolecular Rapid Communications ,2004,25 ( 12 ) : 1197 - 1202.
  • 10胡水,董志华,温世鹏,等.稀土钆有机配合物合成工艺及其橡胶复合材料射线屏蔽性能[C]∥中国化学会高分子学科委员会.2009年全国高分子学术论文报告会论文摘要集(下).天津:中国化学会高分子学科委员会,2009.

共引文献73

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部