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纳米金在若干化学反应中的催化应用

Application of nanogold catalyst in several chemical reactions
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摘要 高度分散的纳米金催化剂作为一个新兴的研究领域,对许多化学反应具有优良的活性。本文概括地介绍了近期发表的关于金负载催化剂成功地用于催化CO氧化、环己烷氧化制环己酮、催化氧化甲醛,、二醇氧化制内酯反应、丙烯直接环氧化、苯甲醇氧化制苯甲醛和氮氧化物还原等反应的例子。 Well-dispersed gold nanocatalysts,as a new field of study,shown to possess very high activity in many reactions. The recent literature concerning CO oxidation, cyclohexane oxidation to cyclohexanone, catalytic oxidation of HCHO, the aerobic oxidative dehydrogenation of diols to lactone, reduction of nitrogen oxides, Direct epoxidation of propylene, Direct conversion of methane to methanol on supported gold catalysts were briefly reviewed in this article.
出处 《化学工程师》 CAS 2013年第2期52-54,共3页 Chemical Engineer
关键词 纳米金催化剂 高分散 选择性氧化 态势分析 nanogold catalyst highly dispersed selective oxidation state analysis
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参考文献11

  • 1Li-Hsin Chang, Yi-Lin Yeh, Yu-Wen Chen. Preferential oxidationof CO in hydrogen stream over nano-gold catalysts prepared byphotodeposition method [j ]. International Journal of Hydrogen Energy,2008, 33:1965-1974.
  • 2何潮洪,徐立信,等.负载型纳米金催化剂上环己烷氧化研究[D].博士论文.
  • 3lvarez-Galv 6 n M C , de la Pe a 0 ’ Shea V A , Fierro J L G, al.Alumina-supported manganese-and manganese-palladium oxidecatalysts for VOCs combustion [ J ] .Catalysis Communications, 2003,4(5) :223-228.
  • 4贾钧琳,王东辉,金佳佳,张泽廷,史喜成.纳米金催化剂低温催化氧化甲醛和一氧化碳的研究[J].北京化工大学学报(自然科学版),2008,35(6):1-5. 被引量:6
  • 5黄捷,戴维林,等.纳米金催化剂的合成及其在二醇氧化制内酯反应中的应用研究[D].博士论文.
  • 6Wang R P, Guo XW, et al. Gas-phase epoxidation of propylene overAg/Ti-containing catalysts. Catal. Today [j J.2004,93-95: 217-222.
  • 7Can Kizilkaya A,Senkan S, Onal I,Investigation of rutheniumcopper bimetallic catalysts for direct epoxidation of propylene: ADFT study [j]. Journal of Molecular Catalysis A: ChemicaI2010, 330:107-111.
  • 8Weisbeck M, Heinen M, Schmitt J,et al. US:20041384802A.
  • 9Hui Wang, Jun Wang, Preparation and catalytic activity of nanometergold ultrafines supported on Co304. Powder Technology,2000,111:175; 178.
  • 10Chen L F,Hu J C, Richards R. Intercalation of aggregation-freewell-dispersed gold nanoparticles into the walls of mesoporoussilica as a robust “green” catalyst for n-alkane oxidation [j ]. J. Am.Chem.Soc.,2009,131(3):914-915.

二级参考文献14

  • 1张鑫,徐柏庆.Au/ZrO_2催化CO氧化反应中ZrO_2纳米粒子的尺寸效应[J].化学学报,2005,63(1):86-90. 被引量:26
  • 2Alvarez-Galvan M C, de la Pena O'Shea V A, Fierro J L G, et al. Alumina-supported manganese-and manganese- palladium oxide catalysts for VOCs combustion [ J ]. Catalysis Communications, 2003, 4(5) : 223 - 228.
  • 3Zhang Changbin, He Hong, Tanaka K. Perfect catalytic oxidation of formaldehyde over a Pt/TiO2 catalyst at room temperature [J]. Catalysis Communications, 2005, 6 (3): 211-214.
  • 4Sekine Y. Oxidative decomposition of formaldehyde by metal oxides at room temperature[J]. Atmospheric Environment, 2002, 36(35) : 5543 - 5547.
  • 5Bamwenda G R, Tsubota S, Nakamura S, et al. The influence of the preparation methods on the catalytic activity of platinum and gold supported on TiO2 for CO oxidation[J]. Catalysis Letters, 1997, 44(1 - 2) :83 - 87.
  • 6Valden M, Lai X, Goodman D W. Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties[J]. Science, 1998, 281(5383): 1647 - 1650.
  • 7Chen M S, Goodman D W. The structure of catalytically active gold on titania [ J ]. Science, 2004, 306 (5694) : 252 - 255.
  • 8Wang Donghui, Hao Zhengping, Cheng Daiyun, et al. Influence of pretreatment conditions on low-temperature CO oxidation over Au/MOx/Al2O3 catalysts[J ]. Journal of Molecular Catalysis A: Chemical, 2003, 200( 1 - 2) : 229 - 238.
  • 9Haruta M, Ueda A, Tsubota S, et al. Low-temperature catalytic combustion of methanol and its decomposed derivatives over supported gold catalyst[J ]. Catalysis Today, 1996, 29(1-4): 443-447.
  • 10Jia Meilin, Shen Yuenian, Li Changyan, et al. Effect of supports on the gold catalyst activity for catalytic combustion of CO and HCHO[J]. Catalysis Letters, 2005, 99(3 - 4) : 235 - 239.

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