摘要
利用二氧化锰（MnO2）纳米材料新颖的化学、物理特性，研究其对三联吡啶钌（Ru（bpy）3^2＋的电致化学发光（ECL）的催化作用，结果发现，纳米MnO2材料在温和的条件且较正的电位（＋O．4V（VS．Ag/AgCl））下可以催化Ru（bpy）33^2＋产生阴极ECL。同时推导了其催化机理，为制备一种新型的高灵敏度的ECLSensor奠定了理论基础。
MnO2 nanomaterials showed novel chemical and physical properties because of their special structure, and the corresponding chemiluminescence （ECL） catalysis of Terpyridine ruthenium were investigated. The results indicate that a novel cathodic ECL of Ru（bpy）33^2＋ would be appeared at positive potential of ＋0.4V（vs. Ag/AgCl） and mild conditions. In this paper, catalytic mechanism of MnO2 nanomaterials was deduced and a theoretical basis for preparing novel ECL Sensor with high sensitivity was provided.
出处
《纳米科技》
2013年第1期17-19,79,共4页
基金
基金项目：国家杰出青年科学基金资助项目（51125023）,国家973项目（2011CB013403）,装甲兵工程学院创新基金项目（2011CJ091）
