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Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl_3·6H_2O/BF_3·(Et)_2O in ethanol 被引量：5

Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl_3·6H_2O/BF_3·(Et)_2O in ethanol
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摘要 Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural （EMF） catalyzed by Lewis acid in ethanol was investigated. It was found that BF3.（Et）20 was favorable for 5-hydroxymethylfurfural （HMF） etherification to EMF. BF3.（Et）20 combination with A1C13.6H20 with the molar ratio of 1 was an effective catalyst system for synthesis of EMF from fructose-based carbohydrates. 55.0%, 45.4% and 23.9% of EMF yields were obtained from fructose, inulin and sucrose under optimized conditions, respectively. Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural （EMF） catalyzed by Lewis acid in ethanol was investigated. It was found that BF3.（Et）20 was favorable for 5-hydroxymethylfurfural （HMF） etherification to EMF. BF3.（Et）20 combination with A1C13.6H20 with the molar ratio of 1 was an effective catalyst system for synthesis of EMF from fructose-based carbohydrates. 55.0%, 45.4% and 23.9% of EMF yields were obtained from fructose, inulin and sucrose under optimized conditions, respectively.
作者 Xiuquan Jia Jiping Ma Penghua Che Fang Lu Hong Miao Jin Gao Jie Xu
机构地区 Dalian National Laboratory for Clean Energy Graduate University of Chinese Academy of Sciences
出处 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2013年第1期93-97,共5页 能源化学（英文版）
基金 the National Natural Science Foundation of China(21233008 and 21203180)
关键词 vcarbohydrates 5-ethoxymethylfurfural CATALYSIS Lewis acid vcarbohydrates 5-ethoxymethylfurfural catalysis Lewis acid
分类号 O643.32 [理学—物理化学]
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参考文献11

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共引文献3

同被引文献40

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引证文献5

二级引证文献9

Journal of Energy Chemistry
2013年 第1期

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