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基于N-BDAVBi的高效率双发光层蓝色OLED

High-efficiency blue-fluorescence N-BDAVBi-based organic light-emitting device with double emission layers
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摘要 采用蓝色有机荧光染料N-BDAVBi作为客体发光材料,将其分别掺入主体材料ADN和DPVBi中形成双发光层,制备了结构为ITO/m-MTDATA(40nm)/NPB(10nm)/ADN:N-BDAVBi(15nm)/DPVBi:N-BDAVBi(15nm)/TPBi(30nm)/LiF(0.6nm)/Al的高效率蓝色有机荧光器件(OLED)。器件的最大电流效率为8.13cd/A,对应色坐标为(0.178,0.302),电流密度为18.81mA/cm2,分别是ADN:N-BDAVBi和DPVBi:N-BDAVBi作为发光层的单发光层结构器件的2.4和1.8倍。器件性能提高主要源于双发光层结构减弱了载流子在界面处的积累,扩大了激子产生区域以及主体与客体之间有效的能量转移。当驱动电压为14V时,双发光层器件的最大亮度为20 620cd/m2。 High-efficiency blue fluorescent organic light emitting devices (OLEDs) with double emission layers (DELs) have been demonstrated with structure of ITO/4,4',4-Tris (N-3-methylphenyl-N-phenyl-amino) triphenylamine (m-MTDATA) (40 nm)/N, N'-Bis(naphthalen-l-yl)-N, Nr-bis(phenyl) benzidine(NPB) / (10 nm) / 9,10-Di (naphth-2-yl) anthracene (ADN) : N- ( 4- ( (E) )-2- ( 6- ( ( E)-4- ( diphenylamino) styryl) naphthalen-2-yl) vinyl) phenyl)-N-phenylbenzenamine ( N-BDAVBi ) ( 15 nm) /4,4 r-Bis ( 2, 2- diphenyl- ether- 1- yl) biphenyl (DPVBi) : N-BDAVBi ( 15 nm) / 2,2', 2- ( 1,3,5- Benzinetriyl) - tris (1-phenyl-l-H-benzimidazole(TPBI)(30 nm)/LiF(0. 6 nm)/A1. N-BDAVBi as blue emitting dopant is doped into ADN host and DPVBi host simultaneously to form DELs. The DEL devices show significant improved efficiency compared with the conventional devices with a single emitting layer (SEL). The maximum current efficiency of 8. 13 cd/A with a Commission International deL'Eclairage (CIE) coordinate of (0. 178,0. 302) at current density of 18.81 mA/cm2 is obtained in DEL device,which is about 140; and 80% greater than that of the devices with ADN:N-BDAVBi and DPVBi:N-BDAVBi as emission layer, respectively. The improvement of the current efficiency is attributed to the reduced accumulation of charge carriers at the interfaces,the expansion of the exciton generation region, and the efficient energy transfer from host to dopant. The maximum luminance of 20 620 cd/m2 has been acieved at 14 V in DEL device. The CIE chromaticity coordinate of DEL device changes only from (0. 181, 0. 308) to (0. 172,0. 292) as the luminance increases from 1000 cd/m2 to 5 000 cd/m2.
出处 《光电子.激光》 EI CAS CSCD 北大核心 2013年第3期445-450,共6页 Journal of Optoelectronics·Laser
基金 国家自然科学基金(10804036) 吉林省基础研究计划基金(20100510) 吉林省自然科学基金(20101512 201215221)资助项目
关键词 电致发光(EL) 荧光 蓝光 双发光层 electroluminescence (EL) fluorescence blue light double emitting layers
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参考文献24

  • 1Tang C W,VanSlyke S A,Chen C H. Electroluminescence of doped organic thin films[J]. J. Appl. Phys., 1989,65(9) : 3610-3616.
  • 2Sun Y R,Giebink N C,Kanno H,et al. Management of sin- glet and triplet excitons for efficient white organic light-e- mitting devices[J] Nature, 2006,440 ( 7086 ) ; 908-912.
  • 3Reineke S, Lindner F, Schwartz G, et al. White organic light-emitting diodes with fluorescent tube efficiency[J]. Nature, 2009,459(7244) :234-238.
  • 4李春,彭俊彪,曾文进.新型TPBI/Ag阴极结构的红色有机发光二极管[J].物理学报,2009,58(3):1992-1996. 被引量:6
  • 5陈珉,张磊,林慧,李青,于军胜.基于PEN柔性衬底的顶发射微腔OLED性能研究[J].光电子.激光,2012,23(6):1063-1066. 被引量:5
  • 6Adachi C,Baldo M A,Thompson M E,et al. Nearly 100% internal phosphorescence efficiency in an organic light-e- mitting device[J]. J. Appl. Phys., 2001,90 (10):5048- 5051.
  • 7Meerheim R, Walzer K, Pfeiffer M, et al. Ultrastable and efficient red organic light emitting diodes with doped transport layers[J]. Appl. Phys. Lett. ,2006,89(6) : 1111- 1113.
  • 8Baldo M A, O" Brien D F, You Y, et al. Highly efficient phosphorescent emission from organic electroluminescent devices[J]. Nature, 1998,395(6698) : 151-154.
  • 9Tsuzuki T,Tokito S. Highly efficient, low-voltage phospho- rescent organic light-emitting diodes using an iridium complex as the host material [J]. Adv. Mater., 2007,19 (2) : 276-280.
  • 10Lee M T,Ohen H H,Liao C H,et al. Stable styrylamine- doped blue organic electroluminescent device based on 2-methyl-9,10-di (2-naphthyl) anthraceneEJ]. Appl. Phys. Lett. , 2004,85 (15) : 3301-3303.

二级参考文献52

  • 1Tang C W, VanSlyke S A, Chen C H 1989 J. Appl. Phys. 63 3610
  • 2Burroughes J H, Bradley D D C, Brown A R, Marks R N, MacKay K, Friend R H, Burn P L, Holmes A B 1990 Nature 347 539
  • 3Hung L S, Tang C W, Mason M G 1997 Appl. Phys. Lett. 70 152
  • 4Chan M Y, Lai S L, Fung M K, Tong S W, Lee C S, Lee S T 2003 Appl. Phys. Lett. 82 1784
  • 5Le Q T, Yan L, Gao Y L, Mason M G, Giesen D .l, Tang C W 2000 J. Appl. Phys. 87 375
  • 6Kurosaka Y, Tada N, Ohmori Y, Yoshino K 1999 Synthetic Met. 1112 1101
  • 7Choi H W, Kim S Y, Kim W K, Lee J L 2005 Appl. Phys. Lett. 87 082102
  • 8Li Y, Zhang D Q, Duan L, Zhang R, Wang L D, Qiu Y 2007 Appl. Phys. Lett. 90 012119
  • 9Cao Y, Yu G, Heeger A 1998 J. Adv. Mater. 10 917
  • 10Deng X Y, Lau W M, Wong K Y, Low K H, Chow H F, Cao Y 2004 Appl. Phys. Lett. 84 3522

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