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含吡啶基的HBC衍生物的合成 被引量：1

Synthesis of HBC Derivative Containing Pyridine
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摘要 以四芳基取代环戊二烯酮2与二烷基取代的二苯乙炔3通过Diels-Alder环加成反应得到六芳基取代苯4。化合物4在路易斯酸催化下通过Scholl环氧化脱氢反应,生成化合物5,5再与4-硼酸吡啶发生Suzuki偶联反应生成目标化合物1。 Hexaarylbenzene derivative 4 was synthesized by Diets - Alder cycloaddition reaction of tetraaryl cyclopen- tadienone 2 with 1,2 -bis （4 -dodecylphenyl）ethyne 3. And the compound 5 was obtained by Scholl cyclodehydrogenation with FeC13, the target compound 1 was successfully synthesized by Suzuki coupling reaction.
作者 尚智慧 张灯青 李贤英 金武松
机构地区 东华大学化学化工与生物工程学院
出处 《广州化工》 CAS 2013年第5期84-85,共2页 GuangZhou Chemical Industry
基金 国家自然科学基金项目(批准号:21172035)
关键词 Scholl反应 SUZUKI偶联反应 六苯并蔻 合成 Scholl reaction Suzuki coupling reaction hexabenzocoronene synthesis
分类号 O625.1 [理学—有机化学]
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参考文献11

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共引文献5

同被引文献5

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广州化工
2013年 第5期

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