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三氟溴乙烯应用研究进展 被引量:1

Progress in Application of Bromotrifluoroethylene
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摘要 三氟溴乙烯是制备多种聚合物的重要单体,如用于制备燃料电池离子交换膜理想单体三氟苯乙烯,制备高效、低GWP值的绿色干蚀气体六氟丁二烯,导航系统用氟溴油等。本文对三氟溴乙烯的合成路线进行简单介绍,重点对其在合成反应中的反应特性,及在下游高附加值产品合成中的应用进行了综述。 Bromotrifluoroethylene is a valuable monomer for the synthesis of various polymers and copolymers. For example, it is used to synthesize trifluorostyrene, one important reagent for proton exchange membrane fuel cells. Hexafluorobutadiene is also manufactured from it, which is efficient and environmental friendly etch gas for dielectric etch processing with smaller global warming potential. The bromotrifluoroethylene telomers are used as flotation and damping fluids in inertial guidance systems. This paper reviews a brief introduction on synthesis methods, and emphasizes on the reaction characteristics of bromotrifluoroethylene and applications in preparation of the downstream products with high added value.
作者 刘武灿 李玲
出处 《浙江化工》 CAS 2013年第2期1-6,9,共7页 Zhejiang Chemical Industry
关键词 三氟溴乙烯 含氟烯烃 应用 bromotrifluoroethylene fluorinated olefins application
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参考文献23

  • 1Carl L Yaws, Satish D Kad. Trifluorobromoethylene [A]. Matheson Gas Data Book. 7th Edition. USA: 2001: 68-72.
  • 2Arthur J Elliott. Bromotrifluoroethylene [A]. Kirk Othmer. Encyclopedia of Chemical Technology. John Wiley & Sons, Inc: 2000: 1-4.
  • 3Chen Q Y. Bromotrifluoroethylene [J]. e-EROS Encyclope- dia of Reagents for Organic Synthesis, 2001: 1-3.
  • 4蔚辰刚,谢冠群,周强,王树华,罗孟飞.MgF_2-AlF_3催化剂用于四氟乙烷裂解制备三氟乙烯[J].工业催化,2012,20(4):56-59. 被引量:7
  • 5陈柏洲.新型陀螺悬浮液——氟溴烷油[J].化工新型材料,1990,18(5):42-43. 被引量:3
  • 6Ross C Terrell. Compositions and methods for producing anesthesia: US, 3666864[P]. 1972-5-30.
  • 7Demiel A The Journal of Organic Chemistry [J]. 1960, 25: 993.
  • 8林永达.多氟烯烃F化学位移与亲核反应性的关系[J].有机化学,1978(2):47-55.
  • 9蒋锡夔,计国桢,施亦群.全氟烯烃加成中的一个竞争途径:烷氧基阴离子对三氟溴乙烯加成后形成的碳阴离子的亲溴反应[J].有机化学,1985(5):400-401.
  • 10施亦群.全氟型烯烃亲核加成中的一个新竞争途径烷氧基阴离子对三氟溴乙烯加成后形成的碳阴离子的亲溴反应[J].应用化学,1985(4):88.

二级参考文献65

  • 1王长杰,郑建华,庞海霞.三氟氯乙烯的生产及应用[J].有机氟工业,2004(4):12-15. 被引量:6
  • 2彭顺金,吴伟卿,李建宗,武利民.氟烯烃共聚合的研究进展[J].现代化工,2005,25(9):21-25. 被引量:2
  • 3王其明.六氟丁二烯的合成[J].有机氟工业,2006(1):14-15. 被引量:9
  • 4-.化工百科全书(第5卷)[M].化学工业出版社,1993.43.
  • 5-.精细化学品辞典[M].化学工业出版社,1989.511.
  • 6东冢崇志.-[J].润滑,1987,32(2):107-107.
  • 7Dedek V,Chvatal Z.Addition of 1,2-dibromo-1-chlorotrifluoroethane to chlorotrifluoroethylene induced by UV-radiation.synthesis of perfluoro-1,3-butadiene and perfluoro-1,3,5-hexatriene[J].J.Fluorine Chem.,1986,31:363-379.
  • 8Karimova N M,Glazkov A A,Ignatenko A V,et al.Synthesis of 1,2,3,4-tetrachlorohexafluorobutane[J].Russ.Chem.Bull.,2004,53:2236-2237.
  • 9Georglevich B V,Sergeyevich K A,Ivanobna O S,et al.Process for production of hexafluorobutadiene and 1,2- dichlorohexafluorocyclobutane:RU,0118462[P].2004-06-15.
  • 10Haszeldine R N,Iserson H.Preparation of fluorine compounds:US,2844636[P].1958-07-22.

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