期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

利用混合配体构筑3d-4f骨架:水热合成、结构和磁性研究(英文)

Employing Mixed Ligands to Construct 3d-4f Framework:Hydrothermal Synthesis,Structure and Magnetic Properties
下载PDF
导出
摘要 在水热条件下通过混合配体合成了一个3d-4f配位聚合物:[DyCo(2,3-pydc)2(C2O4)0.5(H2O)3].3H2O。通过单晶X-射线衍射仪确定了该配合物的结构信息,进一步利用元素分析、红外光谱、热重对其进行了表征,测定了配合物的磁性质。 A mixed-ligand 3d-4f coordination polymer, namely, [DyCo （2, 3-- pydc）2 （C2O4）0.5 （H2O）3]· 3H2 O, has been synthesized under hydrothermal condition. Its structure has been determined by single--crystal X ray diffraction analyses and further characterized by elemental analyses, IR spectra, thermogravimetric （TG） analy ses and magnetic study.
作者 刘洋 冯泳兰 陈志敏 李俊华
机构地区 衡阳师范学院化学与材料科学系
出处 《衡阳师范学院学报》 2012年第6期47-50,共4页 Journal of Hengyang Normal University
基金 The Open Research Fund of the Key Laboratory in Hunan Province(grant NO.10k01 and the Doctoral Fund of Hengyang Normal University(grant NO.10B65))
关键词 3D多孔聚合物 水热合成 3d-4f金属有机骨架 磁性 3D porous polymers hydrothermal synthesis 3d-4f MOFs magnetic property
分类号 O431.2 [机械工程—光学工程]
  • 相关文献

参考文献15

  • 1Kagan H. Introduction: frontiers in lanthanide chemistry[J]. Chem. Rev, 2002, 102: 1805-1806.
  • 2Wickleder M. Inorganic lanthanide compounds with complex anions[J]. Chem. Rev., 2002, 102(6): 2011- 2088.
  • 3Lombardi J, Davis B. Periodic properties of force constants of small transition-metal and lanthanide clusters [J]. Chem. Rev., 2002, 102(6):2431-2460.
  • 4Barbour L. Crystal porosity and the burden of proof [J]. Chem. Commun. , 2006, 1163-1168.
  • 5Imdert D, Cantuel M, Btinzli J C G, et al. Extending lifetimes of lanthanide-based near-infrared emitters (Nd, Yb) in the millisecond range through Cr(III) sensitization in discrete bimetallic edifices [J]. J. Am. Chem. Soc. , 2003, 125(51): 15698-15699.
  • 6Guillou O, Daiguebonne C, Camara M, et al. New 3-D La(Ⅲ)-Cu (Ⅱ)-containing coordination polymer with a high potential porosity [J]. Inorg. Chem, 2006, 45 (21):8468-8470.
  • 7Mori F, Nyui T, Ishida T, et al. Oximate-bridged trinuclear Dy-Cu-Dy complex behaving as a single-molecule magnet and its mechanistic investigation [J]. J. Am. Chem. Soc, 2006, 128(5): 1440-1441.
  • 8Gao H L, Zhao B, Zhao X Q, et al. Structures and magnetic properties of ferromagnetic coupling 2D Ln-M heterometallic coordination polymers (Ln = Ho, Er; M = Mn, Zn) [J]. Inorg. Chem, 2008, 47 (23): 11057-11061.
  • 9Luo F, Yang Y T, Che Y X, et al. Construction of Cu (Ⅱ) - Gd(Ⅲ) metal - organic framework by the introduction of a small amino acid molecule: hydrothermal synthesis, structure, thermostability, and magnetic studies [J]. Cryst Eng Comm, 2008, 10: 1613-1616.
  • 10YangYT, LuoF, CheYX, etal. Employing an un-precedented ferromagnetic molecular building block (MBB) of [Co2 Ln(μ3-OH) (CO2)5 (N3)]2 (Ln = Tb, Gd, Dy, Eu, Sin) to construct a 6-connected α-Po Net [J]. Crystal Growth & Design, 2008, 8 (10): 3508-3510.
衡阳师范学院学报
2012年 第6期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部