二氰基二硫纶·邻菲罗啉二酮合铜()配合物的热分解非等温动力学研究

Studies on Non-isothermal Kinetics of Thermal Decomposition of Cu(mnt)(phen-5,6-dione) complexe

应用 Achar法和 Coats-Redfern法对二氰基二硫纶·邻菲罗啉二酮合铜( ) ( Cu( mnt) ( phen-5 ,6-dione) )功能性配合物的热分解过程及其非等温热解动力学进行了研究 ,导出了相应的动力学补偿效应表达式。

The thermal decomposition of Cu(mnt)(phen 5,6 dione) complexe and their kinetics were studied under non isothermal condition by TG and DTG techniques, the non isothermal data were analyzed by means of Achar method and Coats Redfern method. Possible reaction mechanism was suggested by comparing kinetic parameters. The mathematical expressions of kinetic compensation effect of the thermal decomposition reaction were obtained.