摘要
应用 Achar法和 Coats-Redfern法对二氰基二硫纶·邻菲罗啉二酮合铜( ) ( Cu( mnt) ( phen-5 ,6-dione) )功能性配合物的热分解过程及其非等温热解动力学进行了研究 ,导出了相应的动力学补偿效应表达式。
The thermal decomposition of Cu(mnt)(phen 5,6 dione) complexe and their kinetics were studied under non isothermal condition by TG and DTG techniques, the non isothermal data were analyzed by means of Achar method and Coats Redfern method. Possible reaction mechanism was suggested by comparing kinetic parameters. The mathematical expressions of kinetic compensation effect of the thermal decomposition reaction were obtained.
出处
《化学世界》
CAS
CSCD
2000年第7期366-368,382,共4页
Chemical World
基金
国家自然科学基金!资助项目
南京大学配位化学国家重点实验室研究基金!资助课题
关键词
二硫纶
邻菲罗啉二酮
热分解
铜配合物
dithiolene
Cu(mnt)(phen 5
6 dione) complexe
thermal decomposition
non isothermal kinetics