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新型无机-有机杂化化合物(C_(10)H_8N_2)[H_3PMo_(12)O_(40)]·H_2O的水热合成及结构表征 被引量：3

Hydrothermal synthesis and structure characterization of a novel inorganic-organic hybrid compound(C_(10)H_8N_2)[H_3PMo_(12)O_(40)]·H_2O
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摘要 利用水热方法合成一种新奇的无机-有机杂化化合物(C10H8N2)[H3PMo12O40].H2O,采用元素分析、红外光谱、热重分析、紫外光谱和X射线单晶结构分析对其进行了表征.结果表明:该化合物属于单斜晶系,P2(1)/n空间群;晶胞参数a=1.149 78nm,b=1.208 85nm,c=1.728 49nm,α=90°,β=103.143 0°,γ=90°,V=2.339 5nm3,Z=2,R1=0.038 8,wR2=0.111 7. A novel inorganic-organic hybrid compound （C10H8 N2） [H3 PMo12O40]·H2O has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, TGA-DSC, UV-Vis and single-crystal X-ray diffraction. Crystal data： monoclinic, space group P2 （1）/n, a=1. 149 78 nm, b=1. 208 85 nm,c=1. 728 49nm,a=90°,β=103. 143 0°,γ=90°,V=2. 3395 nm3,Z=2,R1 =0. 038 8, wR2 =0.1117.
作者 张科 王明辉 梁大栋 曲楠 刘岩 华成江 钟双玲 栾国有
机构地区 吉林农业大学资源与环境学院
出处 《东北师大学报（自然科学版）》 CAS CSCD 北大核心 2013年第1期93-96,共4页 Journal of Northeast Normal University(Natural Science Edition)
基金 国家自然科学基金资助项目(2110605) 吉林农业大学科研启动基金资助项目(201218)
关键词 多金属氧酸盐 无机-有机杂化化合物 晶体结构 水热合成 polyoxometalate inorganic-organic hybrid compound crystal structure hydrothermal synthesis
分类号 O611.4 [理学—无机化学]
  • 相关文献

参考文献17

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共引文献13

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东北师大学报（自然科学版）
2013年 第1期

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