期刊文献+

新型液体钠锌热稳定剂在聚氯乙烯中的应用研究 被引量:5

Research on Application of Novel Liquid Na/Zn Thermal Stabilizer in Poly(vinyl chloride)
下载PDF
导出
摘要 采用热老化烘箱法和电导法研究了一种新型液体钠锌热稳定剂在聚氯乙烯(PVC)中的应用,并进行了热稳定性、力学性能、热分解动力学性能的研究。结果表明,当钠、锌离子质量比(Na/Zn)=1/1时,PVC热稳定时间达到48min,表现出优良的长期热稳定性;添加该热稳定剂的PVC软制品具有优良的力学性能;液体钠锌热稳定剂的加入使PVC的稳定性得到显著增强。 A A highly efficient and low cost novel liquid Na/Zn thermal stabilizer was developed in this work. Its application in poly(vinyl chloride)(PVC) was investigated by heat aging test and conductivity test. In comparison with pure PVC, the thermal stability time of PVC films was extended to 48 min though adding Na/Zn thermal stabilizer at a Na/Zn mass ratio of 1/1. The dynamic thermogravimetric analysis also confirmed that the Na/Zn stabilizer presented an obvious improvement of stability on thermal degradation. Besides, the Na/Zn stabilizer provided soft PVC with excellent mechanical properties.
出处 《中国塑料》 CAS CSCD 北大核心 2013年第3期77-81,共5页 China Plastics
基金 江苏省产学研联合创新资金(BY2010118)
关键词 聚氯乙烯 钠锌热稳定剂 力学性能 热稳定性 poly (vinyl chloride) sodium/zinc thermal stabilizer mechanical property thermal stability
  • 相关文献

参考文献9

  • 1李杰,刘芳,夏飞.塑料热稳定剂的无铅化技术发展趋势[J].中国塑料,2011,25(12):1-6. 被引量:8
  • 2宋银银,徐会志,蒋平平,刘小林,汪佳二.PVC热稳定剂的发展趋势[J].塑料助剂,2010(4):1-7. 被引量:20
  • 3Xiuqin Xiang, Shuangjun Chen, Jun Zhang. Effect of Rel- atively Nontoxic Thermal Stabilizers on Photodegradation of Poly(vinyl chloride) [J]. Polymer Engineering & Sci- ence, 2010, 50(6): 1095-104.
  • 4刘建平,方廉,宋霞.PVC热稳定剂的现状与发展[J].中国塑料,2001,15(1):15-18. 被引量:39
  • 5刘朋,蒋平平,郭朝彬,薛华,陈慧园,苗红艳.液体PVC热稳定剂异辛酸镁/锌制备及应用性能研究[J].塑料助剂,2012(4):33-39. 被引量:8
  • 6Yanbin Liu, Weiqu Liu, Menghua Hou. Metal Dicarboxy- lares as Thermal Stabilizers for PVC[J]. Polymer Degra- dation and Stability, 2007, 92(8) : 1565-1571.
  • 7Shumin Li, Youwei Yao. Effect of Thermal' Stabilizers Composed of Zinc Barbiturate and Calcium Stearate for Rigid Poly(vinyl chloride) [J]. Polymer Degradation and Stability, 2001, 96(4): 637-641.
  • 8Doyle C D J. Kinetic Analysis of Thermogravimetric Data[J]. Journal of Applied Polymer Science, 1961, (5) : 285-292.
  • 9Minsker KS, Kolosev SV, Zaikov GE. Degradation and Stabilization of Vinyl-chloride-based Polymers[M]. Ox- ford: Pergamon Press, 1988: 950-956.

二级参考文献68

共引文献70

同被引文献80

  • 1付勰,皮红,郭少云.PVC材料抗紫外老化研究进展[J].聚氯乙烯,2008,36(10):1-5. 被引量:4
  • 2杨辉,齐暑华,杨贵忠,冯子煜.高效无毒环保型稀土稳定剂的制备及应用[J].塑料工业,2004,32(11):52-54. 被引量:13
  • 3刘颖,张卫勤,黄锐.多功能稀土稳定剂在PVC中的应用[J].塑料工业,2005,33(B05):186-189. 被引量:16
  • 4寇俊莉,林彦军,王明明.无毒PVC热稳定剂的研究现状与发展趋势[J].中国氯碱,2006(2):1-5. 被引量:10
  • 5石巍,张军.聚氯乙烯紫外光稳定性研究进展[J].塑料科技,2007,35(2):88-95. 被引量:16
  • 6Jiang Pingping, Song Yinyin, Dong Yuming, et al. Zinc Glycerolate with Lanthanum Stearate to Inhibit the Ther- mal Degradation of Poly(vinyl chloride) [J]. Journal of Applied Polymer Science, 2013, 127(5): 3681-3686.
  • 7Mona M Fahmy, Riham R Mohamed, Nadia A Mohamed. Novel Antimicrobial Organic Thermal Stabilizer and Co- stabilizer for Rigid PVC[J]. Molecules, 2012, 17 (7).. 7927-7940.
  • 8Anders S Carlsson, Jenny Lindberg Yilmaz, Allan G Green, et al. Replacing Fossil Oil with Fresh Oil with What and for What[J]. Journal of Thermal Analysis and Calorimetry, 2011, 113(7): 812-831.
  • 9D Balkose, T O Egbuchunam, F E Okieimen. Thermal Behaviour of Metal Soaps from Biodegradable Rubber Seed Oil[J]. Journal of Thermal Analysis and Calorimetry, 2010, 101(2).. 795-799.
  • 10B Kollbe Ahn, Stefan Kraft, D Wang, et al. Thermally Stable, Transparent, Pressure-sensitive Adhesives from Epoxidized and Dihydroxyl Soybean Oil[J]. Biomacromole- cules, 2011, 12(5): 1839-1843.

引证文献5

二级引证文献32

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部