氰基修饰的新型寡聚噻吩衍生物的合成

Synthesis of Novel Oligothiophene Derivatives Modified by Cyano Group

下载PDF

导出

摘要以2,3,4,5-四碘代噻吩为起始原料,利用Suzuki偶联反应来构筑分子骨架,合成了3个氰基和烷基修饰的新型寡聚噻吩衍生物,其结构经1H NMR,13C NMR,EI-MS和元素分析表征。 Three novel cyano group and alkyl modified oligothiophene derivatives were designed and synthesized from 2,3,4,5-tetra iodothiophene by Suzuki coupling reaction used to construct the oligo- thiophene backbone. The structures were characterized by 1H NMR, 13C NMR, EI-MS and elemental analysis.

作者王静

机构地区商丘师范学院化学化工学院

出处《合成化学》 CAS CSCD 北大核心 2013年第2期197-199,共3页 Chinese Journal of Synthetic Chemistry

基金国家自然科学基金资助项目(21102087)

关键词聚噻吩氰基 SUZUKI偶联反应合成 oligothiophene cyano group Suzuki coupling reaction synthesis

分类号 O626.12 [理学—有机化学]

引文网络
相关文献

参考文献16

1Mitschke U, Batierle P. The electroluminescence of organic materials [ J ]. J Mater Chem ,2000,10 : 1471 - 1507.
2Kraft A, Grimsdale A C, Holmes A B. Electrolumi- nescent conjugated polymers seeing polymers in a new light [ J ]. Angew Chem Int Ed, 1998,37 : 402 - 428.
3Robinson M R, Wang S, Bazan G C, et al. Electrolu- minescence from well-defined tetrahedral oligophenyle- nevinylene tetramers [ J ]. Adv Mater, 2000,12 : 1701 - 1704.
4Fachetti A, MushrushM, Katz H E, et al. n-Type building blocks for organic eloctronics:A homologous family of fluorocarbon-substituted thiophcne oligomers with high carrier mobility [ J ]. Adv Mater, 2003,15 : 33 - 38.
5Facchetti A, Yoon M H, Stern C L, et al. Building blocks for n-type molecular and polymeric electronics. Pertluoroalkyl-versus alkyl-funcfionalized oligothiophenes ( ntis; n = 2 - 6). Systematic synthesis, spectroscopy, e- lectrochemistry, and solid-state organization [ J ]. J Am Chem Soc ,2004,126 : 13480 - 13501.
6Sakamoto Y, Suzuki T, Miura A, et al. Synthesis, characterization, and electron-transport property of perfluorinated phenylene dendrimers [ J ]. J Am Chem Soc,2000,122 : 1832 - 1833.
7Bao Z, Lovinger A J, Brown J. New air-stable n-chan- nel organic thin film transistors [ J ]. J Am Chem Soc, 1998,120:207 - 208.
8Tonzola C J, Alam M M, Kaminsky W, et al. New n- type organic semiconductors:Synthesis, single crystal structures, cyclic voltammetry, photophysics, electron transport, and electroluminescence of a series of diphe- nylanthrazolines [ J ]. J Am Chem Soc, 2003, 125 : 13548 - 13558.
9Strukelj M, Papadimitrakopoulos F, Miller T M, et al. Design and application of electron-transporting or- ganic materials [ J ]. Science, 1995,267 : 1969 - 1972.
10Thompson B C, Fr6chet J M J. Polymer-fullerene composite solar cells[ J]. Angew Chem Int Ed ,2008, 47:58 - 77.

1王柳,巨修练.2,5-二取代-1,3,4-噁二唑类杂环化合物的合成、表征[J].武汉工程大学学报,2010,32(5):34-37. 被引量：1
2王静,宋富强.新型四苯乙烯衍生物的合成[J].合成化学,2015,23(11):1053-1055. 被引量：2
3顾成浩,王涛,唐小丽,徐亮,余义开,李柔.基于室温条件及无金属催化的多组分反应构建4-氨基-2-烷基-6-苯基-5-腈基嘧啶分子骨架[J].江西师范大学学报（自然科学版）,2016,40(2):174-178.
4张成仁,巨修练.2-取代杂环化合物的合成[J].合成化学,2008,16(1):56-59.
5齐彦兴,高海翔,蔡利萍,杨敏,索继栓.1,1,3,3-四甲基胍基衍生物的合成及其与二酸的分子识别性能研究(英文)[J].合成化学,2004,12(2):103-107.
6彭化南,余泗莲,余斌,周安西,吴青海,郑大贵.(S)-2-氨基-1,1-二苯基-1-丙醇的合成[J].合成化学,2010,18(1):107-109.
7周光远,程大军,金国新.取代茚基的茂金属Ti、Zr化合物的合成及其催化乙烯聚合活性[J].应用化学,2001,18(2):128-130.
8陶春元,余淑娴,谢宝华,严平,吕正荣.(4S)-4-羧基杂氮硅三环的合成[J].有机化学,1997,17(2):176-179. 被引量：1

合成化学

2013年第2期

浏览历史

内容加载中请稍等...

氰基修饰的新型寡聚噻吩衍生物的合成

参考文献16

相关作者

相关机构

相关主题

浏览历史