期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

Zr-Al-Co-Cu块状金属玻璃晶化相的TEM研究 被引量：1

TEM study of the crystallization phases of Zr-Al-Co-Cu bulk metallic glasses
下载PDF
导出
摘要 采用非自耗电弧炉铜模吸铸方法制备成分为Zr55.8Al19.4Co17.4Cu7.4块状金属玻璃。利用DSC设备在873K时退火,制备该成分的晶化样品。XRD和TEM测试结果表明,金属玻璃过冷液体的晶化产物是一个为Al2CoZr6相(a=0.79nm,c=0.68nm),另一个为底心正交结构的未知相(a=1.32nm,b=0.81nm,c=0.69nm)的混合物。 Zr55 s Al19.4 COLT. 4 Cu7. 4 bulk metallic glasses （BMG） were successfully fabricated through vacuum arc melting furnace under argon gas atmosphere with suction-casting into a water-cooling-copper mold. Crystallization specimens were annealed at 873K using differential scanning calorimetry （DSC） and investigated by X-ray diffractometer and transmission electron microscopy. The results showed the crystallization counterparts were the mixture of two phases, one known A12 CoZr6 phase （ a = 0.79 nm, c = 0. 68 nm） and an unknown base-centered-orthorhombic phase（a = 1.32 nm ,b =0. 81 nm,c =0. 69 nm）. The two phases are structurally very complex.
作者 赵兵兵 李春艳 王英敏 石勇 董闯
机构地区 大连理工大学三束材料改性教育部重点实验室 大连理工大学材料环境学院
出处 《电子显微学报》 CAS CSCD 2013年第1期14-17,共4页 Journal of Chinese Electron Microscopy Society
基金 国家自然科学基金资助项目(No.51131002 No.51178076)
关键词 Zr-Al-Co-Cu 块状金属玻璃 晶化相 Zr-A1-Co-Cu bulk metallic glasses crystallization phases
分类号 TG139.8 [一般工业技术—材料科学与工程]
  • 相关文献

参考文献6

  • 1Liveira M F, Botta F J, Kaufman M J. Phase formed during crystallization of Zrss AILo Ni5 Cu3o metallic glass containing oxygen [ J ]. Journal of Non-crystalline Solids, 2002, 304 : 51 - 55.
  • 2Nagase T, Tmakosh Y. Electron irradiation induced crystallization of the amorphous phase in ZrssA17 5Nil0Cu7 metallic glass [ J ]. Science and Technology of Advanced Materials, 2004, 5:57-67.
  • 3Sheek C H, Wang Y M, I)ong C. The e/a-constant Hume-Rothery phase in an as-cast Zra5 AIT. s NioCuLT. alloy[J]. Materials Science and Engineering A, 2000, 291(1 -2) :78 -85.
  • 4Mukherjee S, Kang H G, Johnson W I,. Nanocontact measurement of crystallization behavior, specific volume, and viscosity of bulk glass-forming Zr-AI-Co - (Ca) alloys [ J ]. I'hysical Review B, 2004, 70: 174205.
  • 5Zhang T, Inoue A. Formation and mechanical strengthof bulk glassy alloys in Zr-A1-Co-Cu system [ J ]. . Materials Transaction JIM, 2002, 43 : 1250 - 1253.
  • 6Zhang T, Inoue A. Formation thermal and mechanicalproperties of bulks glassy alloys in Zr-A1-Co and Zr-A1- Co-Cu system [ J]. Materials Science and Engineering A ,2004, 375 - 377:432 - 435.

同被引文献20

  • 1惠希东,陈国良.块体非晶合金[M].北京:化学工业出版社,2007.
  • 2Telford M. The case for bulk metallic glass[J] . Materials Today, 2004, 7 (3) : 36 - 43.
  • 3Inoue A, Takeuchi A. Recent development and application products of bulk glassy alloys[J]. Acta Materialia, 2011,59(6): 2243 -2267.
  • 4Zhang T, Inoue A, Masumoto T. Amorphous Zr- AI- TM ( TM = Co, Ni, Cu) alloys with significant supercooled liquid region of over 100 K[J]. Mater TransJIM, 1991, 32( 11) : 1005 -1010.
  • 5Peker A,Johnson W L. A highly processable metallic glass: ZrTiCuNiBe[J] . Applied Physics Letters, 1993, 63: 2342.
  • 6Inoue A, Zhang T, Kim Y H. Synthesis of high strength bulk amorphous Zr-AI-Ni-Cu-Ag alloys with a nanoscale secondary phase[J] . Materials Transactions,JIM (Japan) ,1997,38(9): 749 -755.
  • 7Inoue A. Stabilization of metallic supercooled liquid and bulk amorphous alloys[J]. Acta Materialia, 2000 , 48 (1) : 279 - 306.
  • 8Inoue A, Kawase D, Tsai A P, et al. Stability and transformation to crystalline phases of amorphous ZrAICu alloys with significant supercooled liquid region[J] . Materials Science and Engineering: A, 1994, 178 (1 - 2): 255 -263.
  • 9Koster U, MeinhardtJ, Roos S, et al. Formation of quasi crystals in bulk glass forming Zr-Cu-Ni-AI alloys[J]. Applied Physics Letters, 1996, 69: 179.
  • 10Chen M, Zhang T, Inoue A, et al. Quasicrystals in a partially devitrified ZrAINiCuAg bulk metallic glass [J]. Applied Physics Letters, 1999, 75: 1697.

引证文献1

电子显微学报
2013年 第1期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部