过渡金属催化卤代芳烃胺化反应的研究进展

Research Advance in Transition-Metal-Catalyzed Amination of Aryl Halides

过渡金属催化卤代芳烃的胺化是合成芳胺化合物的重要方法,本文综述了近年来过渡金属催化卤代芳烃与胺等不同含氮化合物的胺化反应研究进展。钯和铜是近几年卤代芳烃胺化反应的热点,重点讨论了钯催化下卤代芳烃与各类胺反应以及铜催化下卤代芳烃胺化反应的研究进展。

Transition - metal - catalyzed amination of aryl halides was one of the most important methods for preparing aromatic amine compounds. The recent progress in transition - metal - catalyzed amination of aryl halides with amines and different nitrogen - containing compounds was reviewed. In recent years, palladium and copper were hot sport for amination of aryl halides. The research progress in the palladium catalyzed aryl halides with all kinds of amine reaction and copper catalyzed amination of aryl halides were discussed.