摘要
Effect of solution concentration on the structures and corrosion inhibition behavior of γ-APS films fabricated on surface of low carbon steel was systematically studied by EIS, RA-IR, and AFM. The experimental results indicated that the impedance ofy-APS silane treated substratcs and the cross-linking degree of γ-APS films gradually increased with the increasing solution concentration. There was some noticeable transformation in molecular orientation and protective performance of y-APS films when solution concentration was above 10vo1%. High cross-linking degree and changes in molecular orientation generated γ-APS films with excellent protective performance and ordered arrangement.
Effect of solution concentration on the structures and corrosion inhibition behavior of γ-APS films fabricated on surface of low carbon steel was systematically studied by EIS, RA-IR, and AFM. The experimental results indicated that the impedance ofy-APS silane treated substratcs and the cross-linking degree of γ-APS films gradually increased with the increasing solution concentration. There was some noticeable transformation in molecular orientation and protective performance of y-APS films when solution concentration was above 10vo1%. High cross-linking degree and changes in molecular orientation generated γ-APS films with excellent protective performance and ordered arrangement.
基金
Funded by the National Natural Science Foundation of China(No.50801057)
the Special Fund for Basic Scientific Research of Central Colleges,China University of Geosciences(Wuhan)(No.007-G1323521109)