金属卟啉仿生催化氧化合成有机化工产品

Synthesis of Organic Chemical Products by Metalloporphyrins-Based Biomimetic Catalytic Oxidation

金属卟啉化合物从结构和性能上都是细胞色素P-450单加氧酶的有效模拟物,该文综述了金属卟啉在仿生催化合成醇、醛、酮、酸、酯、环氧化物、亚砜及亚胺等有机化工产品中的应用,认为仿生催化氧化技术在化学工业中将面临重要的发展机遇。

Metalloporphyrins compounds are the effective simulants of the cytochrome P -450 monooxygenase in terms of structures and performance. The synthesis of organic chemical products such as alcohols, aldehydes, ketones, acids, esters, epoxides, sulfoxides and imines by metalloporphyrins- based biomimetic catalytic oxidation is reviewed. The biomimetic catalytic oxidation technology will be facing important developing opportunities in the chemical industry.