摘要
利用电磁悬浮和快淬实验研究Cu60Co30Cr10合金在亚稳不混溶区的液相分离和快速凝固特征。结果表明,合金的显微组织为富(Co,Cr)相分布在富Cu相基体中,且富(Co,Cr)相颗粒的形状和大小随着冷却速率的变化而有明显的区别。在悬浮凝固条件下冷却速率较低,富(Co,Cr)相较粗大,有明显的聚集粗化趋势,富(Cu)相中有大量富(Co,Cr)相枝晶。而在快淬凝固条件下富(Co,Cr)相明显细化,富(Cu)相中未发现富(Co,Cr)相枝晶形成,这可能与较高的冷却速率、较大的过冷度和较高的界面张力有关。
Metastable liquid phase separation and rapid solidification in a metastable miscibility gap were investigated on the Cu60Co30Cr10 alloy by using the electromagnetic levitation and splat-quenching.It is found that the alloy generally has a microstructure consisting of a(Co,Cr)-rich phase embedded in a Cu-rich matrix,and the morphology and size of the(Co,Cr)-rich phase vary drastically with cooling rate.During the electromagnetic levitation solidification processing the cooling rate is lower,resulting in an obvious coalescence tendency of the(Co,Cr)-rich spheroids.The(Co,Cr)-rich phase shows dendrites and coarse spheroids at lower cooling rates.In the splat quenched samples the(Co,Cr)-rich phase spheres were refined significantly and no dendrites were observed.This is probably due to the higher cooling rate,undercooling and interface tension.
基金
Projects(51171152,50871088) supported by the National Natural Science Foundation of China
Project(20126102110048) supported by Doctoral Fund of Ministry of Education of China
Project(SKLSP201202) supported by Foundation of State Key Laboratory of Solidification,China
Project(2012JC2-02) supported by Natural Science Basic Research Plan in Shaanxi Province,China
Project (JC201268) supported by the NPU Foundation for Fundamental Research,China
关键词
Cu-Co-Cr合金
快速凝固
亚稳液相分离
电磁悬浮
快淬
Cu-Co-Cr alloy
rapid solidification
metastable liquid phase separation
electromagnetic levitation
splat-quenching