摘要
研究了采用火试金法直接测定冰铜中的金的含量,确定了最佳实验条件。在氧化铅加入量达到铜量的35倍、硼砂加入量为15g、溶剂样品与Na2CO3比为1∶0.7的条件下,且熔融温度为1 100℃、恒温温度为1 200℃、恒温时间为30min时样品富集分离熔融制备的铅扣效果最好。分析了5个冰铜实际样品,并与原子吸收光谱法进行对比,研究结果表明:方法分析冰铜中的金含量时,分析结果与原子吸收光谱法分析值相吻合,加标回收率为90%～107%。方法的相对标准偏差为2.4%～4.9%。
The direct determination of gold content in matte by fire assaying was studied.The optimal experiment conditions were obtained.When the added amount of lead oxide was 35 times of copper,the added amount of sodium borate was 15 g,the ratio of solvent sample and Na2CO3 was 1∶0.7,the melting temperature was 1 100 ℃,the constant temperature was 1 200 ℃,and the constant temperature time was 30 min,the sample enrichment,separation and prepared lead button by melting were best.Five actual matte samples were analyzed.The results were compared with those obtained by atomic absorption spectrometry.It was found that,the analysis results of gold content in matte by this method were consistent with those obtained by atomic absorption spectrometry.The recoveries of standard addition were 90%-107%.The relative standard deviation（RSD） was 2.4 %-4.9 %.
出处
《冶金分析》
CAS
CSCD
北大核心
2013年第3期69-72,共4页
Metallurgical Analysis
关键词
火试金法
铅扣
冰铜
金
重量法
fire assaying
lead button
matte
gold
gravimetry
