砷、锑、铋的氨荒酸类配合物的研究进展

Research Progress on Chemistry of Arsenic, Antimony and Bismuth Complexes with Dithiocarbamate

综述了近年来合成的三价和五价砷、锑、铋的氨荒酸配合物,包括均配、非均配氨荒酸配体配合物等,在这些配合物中观察到了结构的多样性和不同的成键方式,并对其合成、特性、应用等方面进行了介绍,并对其进行了展望。

The chemistry of both tri- and penta-valent complexes of arsenic, antimony and bismuth derived from dithiocarbamate based ligand have been reviewed in recent years, including homoleptic, nonhomoleptic bis（dithiocarbamate） and mon（dithiocarbamate） complexes. A variety of structural pat- terns and different bonding modes of ligands have been observed in these complexes, synthesis, proper- ties, structural aspects and applications of their compounds have also been described. And the prospect of development and investigation in this field is also brought forward.