摘要
有机-无机杂化材料兼具有机材料和无机材料的优点,是继单组份材料、复合材料和梯度材料之后的新一代功能材料。基于可以通过分子设计与剪裁的倍半硅氧烷(笼型倍半硅氧烷和无规倍半硅氧烷)无机前驱体,利用多种方法如反应性共混法、溶胶-凝胶法、光固化、原子转移自由基聚合、自组装技术等制备一系列高性能聚合物/倍半硅氧烷有机-无机纳米杂化材料。
Organic-inorganic hybrids, combining the advantages of organic materials and inorganic materials, are a new generation functional materials following the one-component material, composites and gradient materials. Based on Polyhedral oligomeric silsesquioxane nanoparticle （POSS） which can be designed and modified, a serious of high performance polymer/POSS hybrid materials were prepared through sol-gel, reactively blending, UV-curving, ATRP, self-assembly method, respectively.
出处
《高分子通报》
CAS
CSCD
北大核心
2013年第4期151-164,共14页
Polymer Bulletin
基金
国家自然科学基金(基金号:20974013
20374007
50203002
51273017)
关键词
笼型倍半硅氧烷
有机-无机杂化材料
高性能
Polyhedral oligomeric silsesquioxane
Organic-inorganic hybrids
High performance
