摘要
系统地测试了 TPP（NO<sub>2</sub>）Cl,TPP（NH<sub>2</sub>）Cl、TPP（NO<sub>2</sub>）-Q 和 TPP（NH<sub>2</sub>）-Q 的萤光发射光谱,红外光谱和核磁共振（<sup>1</sup>H）谱,根据图谱,分别计算了各种光谱数据或进行了经验归属.确认了各种被测化合物的结构,并肯定了用作光—电转换材料的基础原料是完全可行的,为下一步工作提供了可靠的实验依据.
In this article,the fluorescent emission spectra,IR spectraand NMR(~1H) spectra of TPP(NO_2)C1,TPP(NH_2)C1,TPP(NO_2)-Q and TPP(NH_2)-Q have been measured systematically.According to these spectra,each kind of spectroscopic data has been,calculated or peaks classified experientially, respectlvely.Then the structures of tested compounds have been affirmed and it has been confirmed that it is fully feasible that they are used as the basic raw material of light-electricity changing material.The reliable experimental bases have been provided for the further work.
关键词
卟啉-苯醌
分子光谱分析
结构
study
fluorescent emission sbectrooby
IR sbectroscopy NMR(~1H)spectroscoby
porphyrin-benzoquinone
