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Fe_2O_3/H_2O_2类芬顿法处理阴离子表面活性剂废水的试验 被引量:6

Experiment of Fenton -Like Fe_2O_3/H_2O_2 Reaction Process for Treatment of Wastewater with Anionic Surfactant
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摘要 摘要该文采用FeEOy/H2O2类芬顿试剂处理阴离子表面活性剂——十二烷基苯磺酸钠(SDBS),研究了H2O2浓度、Fe2O3投加量、pH值及反应温度对处理效果的影响,结果表明SDBS的降解率随温度的升高而升高;当Hz02/Fe203=1.568(物质的量比)时体系具有较高的降解率;pH对体系降解率影响不大,在2~10的范围内降解率均较高;Fe2O3/H2O2非均相体系类Fenton试剂和Fe2+/H2O2均相体系Fenton试剂的降解效果相差不大,但前者具有pH范围宽,易分离,不产生二次污染的特点。 Abstract Fe2O3/H2O2, a kind of Fenton-like agent, was used to degrade sodium dodecyl benzene sulfonate (SDBS). Effect of H2O2 eoncentration, Fe2O3 dosage, pH value and reaction temperature on SDBS degradation was studied. Results show the degradation of SDBS increases with temperature increasing. The SDBS degradation ratio is high when H2O2/Fe2O3 is 1.568. pH value has unmarked effect on degradation of system. When pH is 2--10, the system maintains high degradation rate. Fenton-like Fe2O3/H2O2 reaction al- most has the same efficiency as homogeneous Fenton reaction, while the former has a widely pH range and Fe2O3 can be separated easily and has no secondary pollution.
出处 《净水技术》 CAS 2013年第2期39-42,73,共5页 Water Purification Technology
关键词 类Fenton法 三氧化二铁(Fe2O3) 双氧水(H2O2) 阴离子表面活性剂 羟基自由基 降解 Fenton-like method ferric oxide (Fe2O3) hydrogen peroxide (H2O2) anionic surfactant hydroxyl freeradical degradation
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