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SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STAR-SHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE AS CORE

SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STAR-SHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE AS CORE
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摘要 Star-shaped oligothiophenes with hexakis（fluoren-2-yl）benzene （HFB） as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1-T3. Star-shaped oligothiophenes with hexakis（fluoren-2-yl）benzene （HFB） as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1-T3.
作者 Yang Zou Yuan Liu Jin-gui Qin 杨楚罗
机构地区 Department of Chemistry
出处 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2013年第6期938-945,共8页 高分子科学（英文版）
基金 supported by the National Science Fund for Distinguished Young Scholars of China(No. 51125013)
关键词 Star-shaped molecules Hexakis（fluoren-2-yl）benzene Oligothiophene Electropolymerization. Star-shaped molecules Hexakis（fluoren-2-yl）benzene Oligothiophene Electropolymerization.
分类号 O631.3 [理学—高分子化学]
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Chinese Journal of Polymer Science
2013年 第6期

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