5-氨基间苯二甲酸与乙酸铜或乙酸钴的机械化学反应研究

Studies on the Mechanochemical Reactions Between 5-Aminoisophthalic Acid and Copper(Ⅱ) Acetate Monohydrate or Cobalt(Ⅱ) Acetate Tetrahydrate

采用振荡式球磨机作为机械能发生装置,分别研究了5-氨基间苯二甲酸(H2AIP)和乙酸铜或乙酸钴的机械化学反应。结果表明,当在振荡式球磨机(20 Hz)中球磨30 min促使生成2维聚合物:[Cu(HAIP)2]H2O和[Co(HAIP)2(H2O)2]2H2O。

In a shaking ball mill,the mechanochemical reactions between 5-aminoisophthalic acid and Cu（OAc）2 H2O or Co（OAc）2 4H2O have been studied.The results show that ball milling of the starting materials in the shaking（at 20 Hz） ball mill,two bidimensional coordination compounds,[Cu（HAIP）2] H2O and [Co（HAIP）2（H2O）2] 2H2O are obtained successfully under neat granding.