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三维超分子化合物[Zn(H_2BTC)_2(phen)]的合成、晶体结构及荧光性质

Synthesis,Crystal Structure and Photoluminescence Property of A Supramolecular Compound [Zn(H_2BTC)_2(phen)]
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摘要 以邻菲罗啉(phen)和1,3,5-苯三甲酸(H3BTC)为配体,与ZnSO4.7H2O在水热条件下合成了一种新的三维波浪式超分子化合物[Zn(H2BTC)2(phen)].该晶体属于单斜晶系,C2/c空间群,晶胞参数为:a=9.917(2)°A,b=15.984(3)°A,c=16.673(3)°A,α=90.00°,β=94.607(4)°,γ=90.00°,V=2634.4(9)°A3,Z=4.中心Zn(II)采取六配位的模式处于一个畸变的八面体几何构型中,并通过分子间O—H…O和C—H…O氢键作用构建成三维超分子结构.研究表明,该配合物具有较好的荧光性质. Under hydrothermal conditions,the reaction of ZnSO4·7H2O with benzene-1,3,5-tricarboxylate（H3BTC） and 1,10-phenanthroline（phen） gave a new supramolecular compound,[Zn（H2BTC）2（phen）].The title compound crystallize in monoclinic system with C2/c space group.Crystal cell parameters are a=9.917（2） A,b=15.984（3） A,c=16.673（3） A.〗,α=90.00°,β=94.607（4）°,γ=90.00°,V=2634.4（9） A3,Z=4.The Zn（II） center in the title compound is six-coordinated,forming a distorted octahedral geometry.The compound presents a 3D supramolecular structure through O—H…O and C—H…O hydrogen bonds.Photoluminescence measurements indicate that the compound has good photoluminescence property.
作者 邵帅 赵慧超 田静 陈晓宇 朱玉兰
机构地区 东北师范大学化学学院 淮阴师范学院化学化工学院
出处 《淮阴师范学院学报（自然科学版）》 CAS 2013年第1期37-41,共5页 Journal of Huaiyin Teachers College;Natural Science Edition
基金 国家自然科学基金资助项目(20671038) 江苏省低维材料化学重点建设实验室开放课题(JSKC11098)
关键词 水热合成 超分子 晶体结构 荧光光谱 hydrothermal synthesis supramolecular crystal structure fluorescence spectra
分类号 O614 [理学—无机化学]
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参考文献17

  • 1Ma K R, Ma F, Zhu Y L. N-heterocyclic amine-directed structures and properties of two Cu(II) Diphosphonates [J]. Dalton Trans, 2011, 40: 9774-9781.
  • 2汤学铃,朱礼文,朱玉兰,陈浩,马凤.三维超分子化合物[CuCl(phen)_2]·H_2SIP·3H_2O的制备及晶体结构[J].淮阴师范学院学报（自然科学版）,2010,9(1):31-34. 被引量：1
  • 3Wang H, Huo L H, Deng Z P, et al. Syntheses, crystal structures and luminescent properties of Zn(II)/Cd(II) supramolecular complexes incorporating 4-sulfinobenzoate and its in situ oxidized ligand [J]. CrystEngComm, 2012, 14:3501 - 3508.
  • 4Kitagawa S, Kitaura R, Noro S. Functional Porous Coordination Polymers [J]. Angew Chem Int Ed, 2004, 43(18): 2334- 2375.
  • 5Janiak C. A critical account on 7t-Tt stacking in metal complexes with aromatic nitrogen-containing ligands [J]. J Chem Soc Dalton Trans, 2000, 21: 3885- 3896.
  • 6Boldog I, Daran J C, Chemega A N, et al. Hydrogen bonding patterns and supramolecular structure of 4,4'-bipyrazolium salts [J]. Cryst Growth Des, 2009, 9(6): 2895-2905.
  • 7Zhao J P, Hu B W, Liu F C, et al. Arenedisulfonate-lanthanide supramolecular architectures with phenanthroline as a eo-ligand: syntheses and structures [J]. Cryst Eng Comm, 2007, 9:902 - 906.
  • 8Accorsi G, Listorti A, Yoesaf K, et al. 1,10-Phenanthrolines: versatile building blocks for luminescent molecules, materials and metal complexes [J]. Chem Soc Rev, 2009, 38(6): 1690- 1700.
  • 9Zhu Y L, Shao S, Ma K R, et al. Syntheses, Structures and Luminescent Properties of Two Novel M(II)-Phen-SIP Supramolecu- lar Compounds (n: Co, Ni) [J]. Bull Korean Chem Soc, 2012, 33(4): 1259- 1263.
  • 10Dias H V R, Diyabalanage H V K, Rawashdeh-Omary M A, et al. Bright Phosphorescence of a Trinuclear Copper(I) Complex: Luminescence Thermochromism, Solvatochromism, and Concentration Iamainochromism [J]. J Am Chem Soc, 2003, 125(40) : 12072- 12073.

二级参考文献12

  • 1Ma K R, Zhu Y L, Yin Q F. Solvothermal synthesis and characterization of a new ZnlI-PMIDA phosphonate [J]. J Coord Chem, 2009, 62(20) : 3243 - 3249.
  • 2Allendorf M D, Bauer C A, Bhakta R K, et al. Luminescent metal-organic frameworks [ J ]. Chem Soc Rev, 2009, 38 (5) : 1330 -1352.
  • 3Li R Q, Zhao P S, Zhu Y L, et al. Synthesis, crystal structures and density functional theory study of dimeric copper(Ⅱ) complexes of a tridentate Schiff-base ligand [J]. Inorg Chim Acta, 2009, 362:4081 -4086.
  • 4Zhang W, Zhao F, Liu T, et al. Spin crossover in a series of iron(Ⅱ) complexes of 2-(2-alkyl-2H-tetrazol-5-yl)-1,10-phenanthroline: Effects of alkyl side chain, solvent, and anion [J]. Inorg Chem, 2007, 46(7): 2541- 2555.
  • 5Yang A H, Zhao L H, Quan Y P, et al. Formation of the water layer in lanthanide coordination polymers with 6-methyl-2,3,5- pyridinetricarboxylate as a novel bridging ligand [J]. Cryst Growth Des, 2010, 10( 1 ): 218- 223.
  • 6Janiak C. A critical account on pi-pi stacking in metal complexes with aromatic nitrogen-containing ligands [J]. J Chem Soc-Dalton Trans, 2000, 21 : 3885 - 3896.
  • 7Boldog I, Daran J C, Chernega A N, et al. Hydrogen bonding patterns and supramolecular structure of 4,4'-bipyrazolium salts [J]. Cryst Growth Des, 2009, 9(6): 2895-2905.
  • 8Accorsi G, Listorti A, Yoosaf K, et al. 1,10-Phenanthrolines: versatile building blocks for luminescent molecules, materials and metal complexes [J]. Chem Soc Rev, 2009, 38(6) : 1690- 1700.
  • 9Sammes P G, Yahioglu G. 1,10-Phenanthroline-A versatile ligand [J]. Chem Soc Rev, 1994, 23(5): 327 - 334.
  • 10Wang Y L, Liu Q Y, Xu L. Syntheses, structures and photoluminescence of two 3D pillared metal-organic frameworks with unique (4(11). 6(4))(4(10). 6(5)) topology based on two kinds of topologically nonequivalent nodes [J]. Inorg them Commun, 2008, 11(8) : 851 - 854.
淮阴师范学院学报（自然科学版）
2013年 第1期

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