纳滤预处理测定景观水体中溶解性有机氮质量浓度及其分布特征

Measurement of Dissolved Organic Nitrogen with Nanofiltration Pretreatment and Its Distribution Characteristics in Landscape Water

为了提高景观水体中DON测定的精确性,研究了纳滤(NF90、NF270)预处理前后水样中DON测定的变化,探讨了NF90、NF270对DIN的去除效果.结果表明,NF90和NF270预处理对NH4+-N、NO3--N和NO2--N的平均去除率分别为30.7%、55.9%、50.0%、73.1%、42.9%、72.0%,NF270对DIN的去除效果更好.常规方法测定DON的质量浓度范围为0.09～0.46 mg·L-1,采样点2处出现负值(-0.08 mg·L-1),DIN/TDN比率范围为85.3%～105%;NF90预处理测定DON的质量浓度范围为0.03～0.58 mg·L-1,DIN/TDN比率范围为76.1%～90.6%;NF270预处理测定DON的质量浓度范围为0.10～0.59 mg·L-1,DIN/TDN比率范围为47.5%～84.5%.这说明NF预处理能够有效去除水样中DIN,减少DON测定的标准偏差,增加了测定的精度.奥林匹克森林公园水体中DON分布的研究表明,水体DON呈现显著的季节性差异,并且南北园区也存在明显差异.北园11月、3月、5月DON较低,小于0.2 mg·L-1,7月质量浓度较高,南园5月DON较低,11月和3月较高,在0.40～0.65 mg·L-1之间.

In this study,we present a nanofiltration（NF90,NF270） pretreatment to increase the precision of dissolved organic nitrogen（DON） measurements in water samples.The variations of DON measurements with and without NF pretreatment were investigated.And the effects on the removal of dissolved inorganic nitrogen（DIN） by NF90 and NF270 were compared.As shown in the results,the average removal rates reached 30.7%,55.9% of NH4＋-N,50.0%,73.1% of NO3--N and 42.9%,72.0% of NO2--N for NF90 and NF270 pretreatment,respectively.NF270 was obviously more effective to remove the DIN species.Concentrations of DON measured using traditional methods varied from 0.09 to 0.46 mg·L-1,with negative concentration（-0.08 mg·L-1） at site 2 and the DIN/TDN ratio ranged from 85.3% to 105%;while the concentrations of DON measurements varied from 0.03 to 0.58 mg·L-1,and the DIN/TDN ratio ranged from 76.1% to 90.6% for NF90 pretreatment and varied from 0.10 to 0.59 mg·L-1,and the DIN/TDN ratio ranged from 47.5% to 84.5% for NF270 pretreatment.The results indicated that nanofiltration pretreatment could effectively remove the DIN species,decrease the standard deviation of DON measurements and increase the precision of DON measurements.The distribution of DON in water samples of Beijing Olympic Forest Park was investigated.The results showed that there was seasonal variation in the concentrations of DON in landscape water from the Olympic Forest Park.And there was significant difference between the north and south part.The DON concentrations were less than 0.2 mg·L-1 in November,March and May and higher in July in the north part,while the DON concentrations were lower in May and higher in November and March in the south part,ranging from 0.40-0.65 mg·L-1.