摘要
Submicrometer-scale ZnO composite aggregate arrays of nanorods and nanoparticles were prepared by simple wet-chemical route and studied as dye-sensitized solar cells （DSSCs） photoanodes. The ZnO composite aggregate arrays significantly improved the efficiency of DSSCs due to their relatively high surface area, fast electron transport, and enhanced light-scattering capability. A short current density （Jsc） of 11.7 mA/cm2 and an overall solar-to-electric energy conversion efficiency （η） of 3.17% were achieved for the ZnO composite aggregate DSSCs, which were much higher than those obtained for the monodisperse aggregate DSSCs （Jsc = 6.9 mA/cm2, r/= 1.51 %） and ZnO nanorod array DSSCs （Jsc = 4.2 mA/cm2, η= 0.61%）.
Submicrometer-scale ZnO composite aggregate arrays of nanorods and nanoparticles were prepared by simple wet-chemical route and studied as dye-sensitized solar cells （DSSCs） photoanodes. The ZnO composite aggregate arrays significantly improved the efficiency of DSSCs due to their relatively high surface area, fast electron transport, and enhanced light-scattering capability. A short current density （Jsc） of 11.7 mA/cm2 and an overall solar-to-electric energy conversion efficiency （η） of 3.17% were achieved for the ZnO composite aggregate DSSCs, which were much higher than those obtained for the monodisperse aggregate DSSCs （Jsc = 6.9 mA/cm2, r/= 1.51 %） and ZnO nanorod array DSSCs （Jsc = 4.2 mA/cm2, η= 0.61%）.
基金
supported by the Changjiang Scholar and Innovative Research Team of the University of China(No. IRT0972)
the National Natural Science Foundation of China (No.51002102)
the Natural Science Foundation of Shanxi Province,China(No.2011011022-1)
the Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi,China
