期刊文献+

FTX催化剂加氢裂化预处理反应性能 被引量:2

Reaction Performance of FTX Catalyst for Pretreatment of Hydrocracking Feedstock
下载PDF
导出
摘要 FTX催化剂是抚顺石油化工研究院(FRIPP)开发的具有高活性的体相超深度加氢脱硫催化剂。FTX加氢催化剂以W-Mo-Ni为加氢活性金属组分,具有活性金属含量高、活性金属分散性好、较大的比表面积和孔体积、活性位中心多的特点,可以处理含有大分子的重质油。200 mL小型加氢装置的评价结果表明,FTX体相催化剂脱氮性能好,活性稳定性好,具有优异加氢裂化预处理性能。工业应用结果表明,在满负荷运转的条件下,能够满足工业装置实际生产要求,可为炼油厂加氢裂化装置扩能增效提供技术保证。 FTX ultra-deep hydrodesulfurization catalyst with high activity was successfully developed by Sinopec Fushun research institute of petroleum and petrochemicals (FRIPP). The catalyst is to use W- Mo-Ni as active metal component for hydrogenation, is characterized by high active metal content, good dispersion of active metals, high specific surface area and pore volume and large number of active sites, may be used to treat poor oil with macromolecule. Evaluation results in 200ml hydrogenation setting illustrate that FTX catalyst has excellent activity of HDN and activity stability, can be applied in hydrocracking pretreatment process. The commercial application indicates that FTX catalyst has excellent hydrodenitrogenation activity under full-load operating conditions, can meet requirements of the actual production in industrial unit, which can provide technical guarantee for improving efficiency and capacity of hydrocracking units.
出处 《当代化工》 CAS 2013年第5期614-616,619,共4页 Contemporary Chemical Industry
关键词 FTX催化剂 加氢裂化预精制 加氢脱氮 工业应用 Hydrocracking pretreatment Bulk Catalyst Commercial application
  • 相关文献

参考文献9

二级参考文献24

  • 1温德荣,喻正南,梁相程,刘永善.FF-26加氢裂化预处理催化剂的研制及工业放大[J].石油炼制与化工,2005,36(6):5-8. 被引量:7
  • 2彭全铸,王继锋,韩崇仁.3936馏分油加氢精制催化剂的开发与应用[J].石油炼制与化工,1996,27(12):18-21. 被引量:8
  • 3李扬,刘继华,牛世坤,李士才.焦化石脑油加氢脱芳烃生产乙烯料[J].炼油技术与工程,2007,37(9):28-30. 被引量:7
  • 4Topsφe H, Clausen B S, Massoth F E. Hydrotreating Catalysis. New York Springer, 1996.1.
  • 5Grange P, Vanhaeren X, Hydrotreating catalysts, an old storywith new challenges. Catal Today, 1997, 36:375.
  • 6Yamada M, Segawa K, Ohtsuka Y. HDS and HDN catalysisfor super clean fuels. Catal Today, 1997, 39:1.
  • 7Kozai S, Kabashima H, Hattori H. Participation of acidic sites on catalysts in hydrodenitrogenation of quinoline. Fuel, 2000, 79: 305.
  • 8Schwartz V, Oyama S T. Reaction network of pyridine hydrodenitrogenation over carbide and sulfide catalysts. J Mol Catal,2000, 163:269.
  • 9刘继华.Fripp生产清洁柴油的临氢催化技术[C]∥加氢技术论文集.抚顺:中国石化抚顺石油化工研究院,2004:60-71.
  • 10Song Chunshan. An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel [ J ]. Catalysis Today, 2003,23:211 - 263.

共引文献29

同被引文献14

引证文献2

二级引证文献5

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部