期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

可光固化单体2,7-二溴-9,9-双[4'-(3″-乙基-3″-氧杂环丁烷甲氧基己基氧基)苯基]芴的合成

Synthesis of Photo-crosslinkable Monomer 2,7-Dibromo-9,9-bis [4′-(3″-ethyl-3″-oxetanylmethyloxyhexyloxyphenyl]fluorene
下载PDF
导出
摘要 以芴为原料,经溴代和氧化反应制得2,7-二溴芴酮(3);3与苯酚反应合成2,7-二溴-9,9-双(4'-羟基苯基)芴(4);4与3-(6'-溴己氧基甲基)-3-乙基氧杂环丁烷经醚化反应合成了可光固化单体2,7-二溴-9,9-双[4'-(3″-乙基-3″-氧杂环丁烷甲氧基己基氧基)苯基]芴,总收率67%,其结构经1H NMR,13C NMR和元素分析表征。 A photo-erosslinkable monomer, 2,7-dibromo-9,9-bis [ 4 ′- （ 3″-ethyl-3″-oxetanylmethyloxy- hexyloxyphenyl） fluorene, was synthesized in total yield of 67% from fluorene by bromination and oxydation, and reaction with phenol to 2,7-dibromo-9,9-bis （4′-hydroxylphenyl） fluorene （4）. Then 4 was reacted with 3-（6′-bromohexyloxymethyl）-3-ethyloxetane. The structures were characterized by 1 H NMR, J3C NMR and elemental analysis.
作者 张晓云 赵蓓 吴伟
机构地区 中国石油大学(华东)理学院化学系
出处 《合成化学》 CAS CSCD 北大核心 2013年第3期336-338,341,共4页 Chinese Journal of Synthetic Chemistry
基金 山东省自然科学基金资助项目(ZR2011BM012)
关键词 氧杂环丁烷 二溴单体 芴 合成 oxetane dibromo monomer fluorene synthesis
分类号 O623.671 [理学—有机化学]
  • 相关文献

参考文献12

  • 1Zacharias P, Gather M C, Rojahn M, et al. New crosslinkable hole conductors for blue-phosphorescent organic light-emitting diodes [ J ]. Angew Chem Int Ed,2007,46 ( 23 ) :4388 - 4392.
  • 2叶霖,高鹏,张晓雯,冯增国,吴锋,陈实,王国庆.氧杂环丁烷开环聚合[J].功能高分子学报,2005,18(4):651-659. 被引量：5
  • 3Mueller C D, Falcou A, Reckefuss N, et al. Multicol- or organic light-emitting displays by solution process- ing [ J ]. Nature,2003, (421 ) : 829 - 833.
  • 4Wettach H, Jester S, Colsmann A, et al. Deep blue organic light-emitting diodes based on triphenylenes [ J ]. Synthetic Metals,2010,160 ( 7 - 8 ) :691 - 700.
  • 5HungM C, LiaoJ L, Chen S A, et al. Fine tuning the purity of blue emission from polydioctylfluorene by end-capping with electron-deficient moieties [ J ]. J Am Chem Soc,2005,127(42) :14576- 14577.
  • 6Wu J R, Chert Y, Wu T Y. Synthesis of copolyflu- orenes with high fluorenone contents and its applica- tion in electroluminescent device by simple lending [ J ]. J App Polym Sci ,2011,119(5 ):2576- 2583.
  • 7Ghaemy M, Barghamadi M. Synthesis and character- ization of novel photoactive polyamide derived from substituted fluorene by copper ( I ) catalyst [ J ]. J App Polym Sci,2009,114(6) :3464 - 3471.
  • 8Tan Y, Gu Z, Kousuke T, et al. Synthesis of block eopolymer based on polyfluorenes and application to lu- minescent materials [ J ]. J Photopolymer Sci Tech, 2011,24(3) :343 - 344.
  • 9Lee M J, Kang M S, Shin M K, et al. Synthesis and characterization of poly I 1,4-bis [ (E) -2-( 3-dodecyl- thiophen-2-yl) vinyl ] benzene t derivatives [ J ]. J Polym Sei, Part A : Polym Chem, 2010,48 ( 18 ) : 3942 - 3949.
  • 10Zhang X, Xuan J, Jiang S S, et al. Highly efficient synthesis of 9-fluorenones from 9H-fluorenes by air ox-idation[ J ]. Green Chemistry, 2011,13 ( 7 ) : 1891 - I896.

二级参考文献18

  • 1麦亦勇,周永丰,颜德岳.超支化聚醚的支化度对玻璃化转变温度的影响[J].高等学校化学学报,2004,25(7):1373-1374. 被引量：4
  • 2Vandenberg E J,Mullis JC,Juvet R S,et al.Poly(3-hydroxyoxetane)-an analog of poly(vinyl alcohol):synthesis,characterization,and properties[J].J Polym Sci:Part A:Polym Chem,1989,27:3113-3149.
  • 3Talukder A H,Lindsay G A.Synthesis and preliminary analysis of block copolymers of 3,3'-bis(azidomethyl)-oxetane and 3-nitratomethyl-3'-methyloxetane[J].J Polym Sci:Part A Polym Chem,1990,28:2393-2401.
  • 4Tomoko F,Umit M,Wynne K J.Synthesis and characterization of novel amphiphilic telechelic polyoxetane[J].Macromol,2003,36:9383-9389.
  • 5Miwa Y,Tsutsumi H,Oishi T.Novel polymer electrolytes based on mono-and bis-oxetane monomers with oligo(ethylene oxide) units[J].Electrochem,2002,70(4):264-269.
  • 6Bronstein L M,Karlinsey R L,Ritter K,et al.Design of organic-inorganic solid polymer electrolytes:Synthesis,structure,and properties[J].J Mater Chem,2004 ,14:1812 -1820.
  • 7Bednarek M,Pencze S K,Kubisa P.Polymerization of hydroxymethyloxetanes synthesis of branched polyethers with primary hydroxyl groups[J].Macromol Symp,2002,177:155-161.
  • 8Bednarek M.Mutihydroxyl branched polyethers by cationic copolymerization of hydroxymethyloxetanes:copolymerization of 3-ethyl-3-(hydroxymethyl)oxetane with difunctional oxetane[J].Polym Int,2003,52:1595-1599.
  • 9Chen Y,Bednarek M,Kubisa P,et al.Synthesis of multihydroxyl branched polyethers by cationic copolymerization of 3,3-bis (hydroxylmethyl)oxetane and 3-ethyl-3-(hydroxylmethyl) oxetane[J].J Polym Sci,Part A:Polym Chem,2002,40(12) :1991-2002.
  • 10Magnusson H,Malmtrom E,Hult A.Influence of reaction conditions on degree of branching in hyperbranched aliphatic polyethers from 3-ethyl-3-(hydroxylmethyl)oxetane[J].Macromol,2001,34:5786-5791.

共引文献4

合成化学
2013年 第3期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部