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可光固化单体2,7-二溴-9,9-双[4'-(3″-乙基-3″-氧杂环丁烷甲氧基己基氧基)苯基]芴的合成

Synthesis of Photo-crosslinkable Monomer 2,7-Dibromo-9,9-bis [4′-(3″-ethyl-3″-oxetanylmethyloxyhexyloxyphenyl]fluorene
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摘要 以芴为原料,经溴代和氧化反应制得2,7-二溴芴酮(3);3与苯酚反应合成2,7-二溴-9,9-双(4'-羟基苯基)芴(4);4与3-(6'-溴己氧基甲基)-3-乙基氧杂环丁烷经醚化反应合成了可光固化单体2,7-二溴-9,9-双[4'-(3″-乙基-3″-氧杂环丁烷甲氧基己基氧基)苯基]芴,总收率67%,其结构经1H NMR,13C NMR和元素分析表征。 A photo-erosslinkable monomer, 2,7-dibromo-9,9-bis [ 4 ′- （ 3″-ethyl-3″-oxetanylmethyloxy- hexyloxyphenyl） fluorene, was synthesized in total yield of 67% from fluorene by bromination and oxydation, and reaction with phenol to 2,7-dibromo-9,9-bis （4′-hydroxylphenyl） fluorene （4）. Then 4 was reacted with 3-（6′-bromohexyloxymethyl）-3-ethyloxetane. The structures were characterized by 1 H NMR, J3C NMR and elemental analysis.
作者 张晓云 赵蓓 吴伟
机构地区 中国石油大学(华东)理学院化学系
出处 《合成化学》 CAS CSCD 北大核心 2013年第3期336-338,341,共4页 Chinese Journal of Synthetic Chemistry
基金 山东省自然科学基金资助项目(ZR2011BM012)
关键词 氧杂环丁烷 二溴单体 芴 合成 oxetane dibromo monomer fluorene synthesis
分类号 O623.671 [理学—有机化学]
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参考文献12

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合成化学
2013年 第3期

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