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不对称氨基锌酞菁的合成与性质 被引量：2

Synthesis,characterization and properties of "doner-accepter" asymmetric amino phthalocyanine zinc
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摘要 以4-硝基邻苯二甲腈、亚氨基二乙酸、二丙胺等化合物为原料,合成了一种不对称氨基锌酞菁,即2(3)-(N,N-二乙酸氨基)-9(10),16(17),23(24)-(N,N-二丙基氨基)锌酞菁(TPC)。通过红外光谱、紫外-可见光谱、元素分析和核磁共振氢谱表征其结构,比较了产物在N,N-二甲基甲酰胺(DMF)溶液及敏化的纳米TiO2薄膜中的紫外-可见光谱;结合紫外-可见光谱、循环伏安曲线和差分脉冲伏安曲线,确定了基态氧化电位和激发态氧化电位能级位置。结果表明,所合成的化合物具有良好的溶解性,一定浓度范围内在DMF中不发生集聚现象,紫外-可见光谱发生明显红移,能级与纳米TiO2薄膜匹配,可用于制备染料敏化太阳能电池。 The synthesis of 2 （3） - （ N, N-two acetic acid amino） -9 （ 10）, 16 （ 17 ） ,23 （24） - （ N, N-dipropyl amine） -phthalocyanine zinc from 4-nitrophthalonitrile was investigated. The complexe was characterized by IR, UV-Vis, elementary analysis and 1H NMR. UV visible absorption spectra in DMF is compared with that adsorbed onto 2 p,m thick TiO2 film. The results show that substituent on phthalocyanine result in the increase of solubility and hindering the dimerization as well as the red shift for UV-Vis of synthesized com- pound.
作者 毛利军 刘晓 成怡 付玲 张学俊
机构地区 中北大学理学院
出处 《山西化工》 2013年第2期1-4,共4页 Shanxi Chemical Industry
基金 山西省高等学校大学生创新创业训练项目资助
关键词 不对称氨基锌酞菁 集聚 合成 表征 能级 asymmetric amino phthalocyanine zinc agglomeration synthesis characterization energy level
分类号 TB34 [一般工业技术—材料科学与工程]
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参考文献11

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二级参考文献5

共引文献7

同被引文献13

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  • 2陈伟,段武彪,贺春英,左霞,吴谊群.两种单氨基取代不对称酞菁锌的合成与表征[J].黑龙江大学自然科学学报,2006,23(5):671-674. 被引量：4
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山西化工
2013年 第2期

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