摘要
Effects of Al- Si addition on hot modulus of rup- ture ~ HMOR) . thermal shock resistance ~ TSR~ . phase composition and mierostructure of low-carbon MgO - C materials were investigated. The results show that: Al and Si addition to low-carbon MgO - C materials leads to dramatic increase in MOR at elevated temperatures; it increases from 4 MPa to 11 -21 MPa at 1 200 ℃ and from 2 MPa to 21 -29 MPa at 1 400 ℃. Al and Si addition to low-carbon MgO - C materials also improves TSR: residual strength ratio after thermal shock when △T = 1 200 ℃ is increased,from 44% to 73% - 77%. Al reacts with C and N2 to form, Al4C3 and AlN, Si reacts with C to form SiC. Ultimately. in-situ formed non- oxides increase appreciably with temperature rising and are well interlaced in periclase skeleton structure at 1 300 -1 400 ℃. which is beneficial to thermomechanical properties.
Effects of Al- Si addition on hot modulus of rup- ture ~ HMOR) . thermal shock resistance ~ TSR~ . phase composition and mierostructure of low-carbon MgO - C materials were investigated. The results show that: Al and Si addition to low-carbon MgO - C materials leads to dramatic increase in MOR at elevated temperatures; it increases from 4 MPa to 11 -21 MPa at 1 200 ℃ and from 2 MPa to 21 -29 MPa at 1 400 ℃. Al and Si addition to low-carbon MgO - C materials also improves TSR: residual strength ratio after thermal shock when △T = 1 200 ℃ is increased,from 44% to 73% - 77%. Al reacts with C and N2 to form, Al4C3 and AlN, Si reacts with C to form SiC. Ultimately. in-situ formed non- oxides increase appreciably with temperature rising and are well interlaced in periclase skeleton structure at 1 300 -1 400 ℃. which is beneficial to thermomechanical properties.