固体聚合物电解质在牛儿醇电化学氧化中的应用

Application of Solid Polymer Electrolyte in Electrooxidation of Geraniol

利用固体聚合物电解质 ( SPE)复合电极 ,将牛儿醇选择氧化为牛儿醛 .为了提高反应的选择性 ,可将 Mn O2 沉积于 Nafion电极上 ,Nafion电极上生成的 Mn O2 将牛儿醇氧化为牛儿醛 ,该反应电流效率较高 .

Solid Polymer Electrolyte (SPE ) composite electrodes were utilized for the selective oxidation of geraniol alcohol to correspondent aldehyde.In order to enhance the reaction selectivity, manganese dioxide was deposited into the Nafion as a mediator.Geraniol was selectively oxidized to correspondentaldehyde with a good currentefficiency.