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2-(间甲氧基)苯基咪唑二羧酸构筑的锌配位聚合物的制备及晶体结构 被引量：3

Synthesis and Crystal Structure of a Zn(Ⅱ) Coordination Polymer from 2-(m-Methoxy)phenyl-imidazole Dicarboxylate
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摘要 采用有机配体2-(3-甲氧基)苯基-4,5-咪唑二羧酸(H3MOPhIDC)和辅助配体邻菲啰啉(Phen)与Zn(Ⅱ)在水热条件下自组装,制得一维配位聚合物[Zn(HMOPhIDC)(Phen)]n.通过元素分析、红外光谱以及X射线单晶衍射对它的分子结构进行表征.结果表明:通过分子间氢键以及π-π堆积力的作用,形成了三维固态超分子结构.该配合物在362℃以下稳定. A one-dimensional coordination polymer, [ Zn （ HMOPhlDC ） （Phen） ] n was prepared through reaction of 2- （3-methoxy） phenyl-4, 5-imidazole dicarboxylic acid （ H3 MOPhIDC ） with Zn （ 11 ） ion under hydrothermal condition. Its molecular structure was characterized by infrared spectroscopy, elemental analysis and X-ray single crystal diffraction. The result showed that by intermolecular hydrogen bonding and π - π stacking interactions, the 3D solid-state supramolecular structure was formed. The complex was thermal stable up to 362 ℃.
作者 贾洪亮 王维康 熊志芳 李纲
机构地区 郑州大学化学与分子工程学院 郑州幼儿师范高等专科学校 郑州大学医学系
出处 《郑州大学学报（理学版）》 CAS 北大核心 2013年第2期85-89,共5页 Journal of Zhengzhou University:Natural Science Edition
基金 国家自然科学基金资助项目 编号21071127
关键词 咪唑二羧酸 锌(Ⅱ) 配位聚合物 晶体结构 imidazole dicarboxylate zinc（ II ） coordination polymer crystal structure
分类号 O614 [理学—无机化学]
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参考文献11

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共引文献4

同被引文献25

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郑州大学学报（理学版）
2013年 第2期

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